COMPARISON OF 2 METHODS FOR COATING PIEZOELECTRIC-CRYSTALS

被引:21
作者
GOMES, MT
DUARTE, AC
OLIVEIRA, JP
机构
[1] Department of Chemistry, University of Aveiro
关键词
QUARTZ CRYSTAL MICROBALANCE; COATINGS; PIEZOELECTRIC CRYSTALS;
D O I
10.1016/0003-2670(94)00361-O
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Quartz piezoelectric crystals were coated with triethanolamine using two procedures: spray and syringe methods. The reproducibility of both coating methods was evaluated comparing the relative standard deviation of batches of four crystals coated by each of the procedures. The relative standard deviation obtained with the spray method is a hyperbolic function of the coating frequency and is, at least, three times lower than the one calculated from results of the syringe method, which is not frequency dependent. An explanation for the poorer reproducibility of the syringe method is given, based on the radial sensitivity theory and the non-uniformity of the coating distribution over the crystal, as evidenced by microscopic photographs.
引用
收藏
页码:329 / 334
页数:6
相关论文
共 8 条
[1]  
BELKOV VM, 1984, ZH ANAL KHIM, V39, P1614
[2]   SYSTEMATIC APPROACH FOR EVALUATION OF TRIETHANOLAMINE AS A POSSIBLE SULFUR-DIOXIDE SORPTION DETECTOR COATING [J].
CHENEY, JL ;
HOMOLYA, JB .
ANALYTICAL LETTERS, 1975, 8 (03) :175-193
[3]   SCANNING ELECTROCHEMICAL MASS SENSITIVITY MAPPING OF THE QUARTZ CRYSTAL MICROBALANCE IN LIQUID-MEDIA [J].
HILLIER, AC ;
WARD, MD .
ANALYTICAL CHEMISTRY, 1992, 64 (21) :2539-2554
[4]   APPLICATIONS OF PIEZOELECTRIC CRYSTAL DETECTOR IN ANALYTICAL-CHEMISTRY [J].
HLAVAY, J ;
GUILBAULT, GG .
ANALYTICAL CHEMISTRY, 1977, 49 (13) :1890-1898
[5]   VELOCITY PROFILE ON QUARTZ CRYSTALS OSCILLATING IN LIQUIDS [J].
MARTIN, BA ;
HAGER, HE .
JOURNAL OF APPLIED PHYSICS, 1989, 65 (07) :2630-2635
[6]   VERWENDUNG VON SCHWINGQUARZEN ZUR WAGUNG DUNNER SCHICHTEN UND ZUR MIKROWAGUNG [J].
SAUERBREY, G .
ZEITSCHRIFT FUR PHYSIK, 1959, 155 (02) :206-222
[7]   EFFECTS OF STRESSED MATERIALS ON THE RADIAL SENSITIVITY FUNCTION OF A QUARTZ CRYSTAL MICROBALANCE [J].
ULLEVIG, DM ;
EVANS, JF ;
ALBRECHT, MG .
ANALYTICAL CHEMISTRY, 1982, 54 (13) :2341-2343
[8]   RADIAL MASS SENSITIVITY OF THE QUARTZ CRYSTAL MICROBALANCE IN LIQUID-MEDIA [J].
WARD, MD ;
DELAWSKI, EJ .
ANALYTICAL CHEMISTRY, 1991, 63 (09) :886-890