FORMATION-CONSTANTS AT HIGH IONIC-STRENGTH .2. THE IONIC-STRENGTH CORRECTION OF FORMATION-CONSTANTS USING A SIMPLIFIED PITZER EQUATION

被引：6
作者：
JACKSON, GE
SEYMOUR, LF
机构：
来源：
TALANTA | 1995年 / 42卷 / 01期
关键词：
D O I：
10.1016/0039-9140(94)00316-K
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A simplified approach to the correction of equilibrium constants from one ionic strength and/or medium to another is developed. A computer program capable of performing these calculations is presented together with results of its application to the NH3/H+, CH3COO-H+, CH3CH2COO-H+, -OOCCH2COO-/H+ and HOOCCH2/H+ systems.
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页码：9 / 16
页数：8
相关论文
共 37 条
[1]  
Beck M.T., 1990, CHEM COMPLEX EQUILIB
[2]   THERMODYNAMICS OF ELECTROLYTES .12. DIELECTRIC PROPERTIES OF WATER AND DEBYE-HUCKEL PARAMETERS TO 350-DEGREES-C AND 1-KBAR [J].
BRADLEY, DJ ;
PITZER, KS .
JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (12) :1599-1603
[3]   Complex formation between carboxylic acids and divalent metal cations [J].
Cannan, RK ;
Kibrick, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :2314-2320
[4]  
DEROBERTIS A, 1985, J CHEM RES-S, P322
[5]   THERMODYNAMIC PARAMETERS FOR THE PROTONATION OF CARBOXYLIC-ACIDS IN AQUEOUS TETRAETHYLAMMONIUM IODIDE SOLUTIONS [J].
DEROBERTIS, A ;
DESTEFANO, C ;
RIGANO, C ;
SAMMARTANO, S .
JOURNAL OF SOLUTION CHEMISTRY, 1990, 19 (06) :569-587
[6]  
DEROBERTIS A, 1985, J CHEM RES M, P629
[7]   TERNARY COMPLEXES IN SOLUTION .44. DEPENDENCE OF AN INTRAMOLECULAR AROMATIC-RING STACKING INTERACTION IN MIXED-LIGAND COPPER(II) COMPLEXES IN AQUEOUS-SOLUTION ON THE DISTANCE OF THE STACKING MOIETY FROM THE COORDINATING GROUP AND THE SOLID-STATE STRUCTURE OF THE TERNARY COPPER(II)-1,10-PHENANTHROLINE PHENYLPROPIONATE COMPLEXIO [J].
DUBLER, E ;
HARING, UK ;
SCHELLER, KH ;
BALTZER, P ;
SIGEL, H .
INORGANIC CHEMISTRY, 1984, 23 (23) :3785-3792
[8]   THE PREDICTION OF MINERAL SOLUBILITIES IN NATURAL-WATERS - THE NA-K-MG-CA-H-CL-SO4-OH-HCO3-CO3-CO2-H2O SYSTEM TO HIGH IONIC STRENGTHS AT 25-DEGREES-C [J].
HARVIE, CE ;
MOLLER, N ;
WEARE, JH .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1984, 48 (04) :723-751
[9]   GADOLINIUM(III) COMPLEX EQUILIBRIA - THE IMPLICATIONS FOR GD(III) MRI CONTRAST AGENTS [J].
JACKSON, GE ;
WYNCHANK, S ;
WOUDENBERG, M .
MAGNETIC RESONANCE IN MEDICINE, 1990, 16 (01) :57-66
[10]   DETERMINATION OF THE STABILITY CONSTANT FOR ACETIC-ACID IN SYNTHETIC SEAWATER MEDIA AT VARIOUS TEMPERATURES AND SALINITIES [J].
JOHANSSON, O ;
WEDBORG, M .
JOURNAL OF SOLUTION CHEMISTRY, 1985, 14 (06) :431-439
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