ACETYLENE COMPLEXES OF DI-(ETA-5-CYCLOPENTADIENYL)MOLYBDENUM - SYNTHESIS AND PROTONATION - STRUCTURE OF [CP2MOH(ETA-2-C2(SIME3)2)]PF6

被引：4
作者：
HERBERICH, GE
ENGLERT, U
FASSBENDER, W
机构：
[1] Institut für Anorganische Chemie der Technischen Hochschule Aachen, W-5100 Aachen
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 03期
关键词：
D O I：
10.1016/0022-328X(91)86457-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cp2MoH2 reacts with methyl acrylate in the presence of acetylenes (L = C2H2, C2Me2, HC = C(t)Bu, HC = CSiMe3, C2(SiMe3)2, HC = CCH2OMe, HC = CCH2NMe2) to form acetylene complexes Cp2Mo(L) 5. Protonation takes place with CF3CO2H at -80-degrees-C to give short-lived cations [Cp2MoH(L)]+ (8) (L = C2Me2, HC = CSiMe3, C2(SiMe3)2). The structure of [Cp2MoH{eta-2-C2(SiMe3)2}]PF6 (9) was determined by an X-ray diffraction study.
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页码：303 / 314
页数：12
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