NEW COPPER CLUSTERS CONTAINING SE AND PET3 AS LIGANDS - [CU70SE35(PET3)22] AND [CU20SE13(PET3)12]

被引：87

作者：

FENSKE, D

KRAUTSCHEID, H

机构：

[1] Institut für Anorganische Chemie, Universität Engesserstrasse, Karlsruhe, D-7500

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The largest cluster so far characterized X-ray crystallographically is formed together with a little 2 (structure: figure on right) in the reaction of CuCl with Se(SiMe3)2 and PEt3. An intermediate en route to 1 could be a Cu9 cluster. On heating 1 to 160-degrees-C Cu2Se is formed.

引用

页码：1452 / 1454

页数：3

共 34 条

[1] COMPLEXES OF 1,5-DI(PARA-TOLYL)-1,4-PENTAAZADIEN-3-IDE, CRYSTAL-STRUCTURES OF [CU(TOLYLNNNNNTOLYL)]3 AND [NI(TOLYLNNNNNTOLYL)2]2
BECK, J
STRAHLE, J
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (05): : 409 - 410
[2] Beck J., 1985, ANGEW CHEM, V97, P419
[3] [CU12S8]4- - A CLOSED BINARY COPPER(I) SULFIDE CAGE WITH CUBOCTAHEDRAL METAL AND CUBIC SULFUR ARRANGEMENTS
BETZ, P
KREBS, B
HENKEL, G
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (04): : 311 - 312
[4] Betz P., 1984, ANGEW CHEM, V96, P293
[5] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [CU(SC6H4-O-SIME3)]12, AN UNUSUAL EXAMPLE OF A PADDLE-WHEEL DODECAMETALLIC THIOLATE CLUSTER
BLOCK, E
GERNON, M
KANG, H
LIU, SC
ZUBIETA, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) : 1031 - 1033
[6] THE TRANSITION FROM MOLECULES TO SOLIDS - MOLECULAR SYNTHESES OF NI9TE6(PET3)8, NI20TE18(PET3)12, AND NITE
BRENNAN, JG
SIEGRIST, T
STUCZYNSKI, SM
STEIGERWALD, ML
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (26) : 9240 - 9241
[7] SYNTHESIS AND STRUCTURE OF THE [NI38PT6(CO)48H6-N]N- (N=5, 4) IONS - NI-PT CLUSTERS AS MODELS FOR CHERRY CRYSTALLITES
CERIOTTI, A
DEMARTIN, F
LONGONI, G
MANASSERO, M
MARCHIONNA, M
PIVA, G
SANSONI, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (08): : 697 - 698
[8] METAL-MERCAPTIDE CHEMISTRY - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE [CU(SC6H5)3]2- ANION - A RATIONAL SYNTHESIS AND THE STRUCTURE OF THE [CU4(SC6H5)6]2- CLUSTER
COUCOUVANIS, D
MURPHY, CN
KANODIA, SK
[J]. INORGANIC CHEMISTRY, 1980, 19 (10) : 2993 - 2998
[9] CRYSTAL AND MOLECULAR-STRUCTURE OF HEXA-(MU2-BENZENETHIOLATO)TETRACUPRATE(I) DIANION
DANCE, IG
CALABRESE, JC
[J]. INORGANICA CHIMICA ACTA, 1976, 19 (02) : L41 - L42
[10] FACKLER JP, 1989, J AM CHEM SOC, V111, P6343

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