NEW COPPER CLUSTERS CONTAINING SE AND PET3 AS LIGANDS - [CU70SE35(PET3)22] AND [CU20SE13(PET3)12]

被引：87
作者：
FENSKE, D
KRAUTSCHEID, H
机构：
[1] Institut für Anorganische Chemie, Universität Engesserstrasse, Karlsruhe, D-7500
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期
关键词：
D O I：
10.1002/anie.199014521
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The largest cluster so far characterized X-ray crystallographically is formed together with a little 2 (structure: figure on right) in the reaction of CuCl with Se(SiMe3)2 and PEt3. An intermediate en route to 1 could be a Cu9 cluster. On heating 1 to 160-degrees-C Cu2Se is formed.
引用
收藏
页码：1452 / 1454
页数：3
相关论文
共 34 条
[1]   COMPLEXES OF 1,5-DI(PARA-TOLYL)-1,4-PENTAAZADIEN-3-IDE, CRYSTAL-STRUCTURES OF [CU(TOLYLNNNNNTOLYL)]3 AND [NI(TOLYLNNNNNTOLYL)2]2 [J].
BECK, J ;
STRAHLE, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (05) :409-410
[2]  
Beck J., 1985, ANGEW CHEM, V97, P419
[3]   [CU12S8]4- - A CLOSED BINARY COPPER(I) SULFIDE CAGE WITH CUBOCTAHEDRAL METAL AND CUBIC SULFUR ARRANGEMENTS [J].
BETZ, P ;
KREBS, B ;
HENKEL, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (04) :311-312
[4]  
Betz P., 1984, ANGEW CHEM, V96, P293
[5]   SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [CU(SC6H4-O-SIME3)]12, AN UNUSUAL EXAMPLE OF A PADDLE-WHEEL DODECAMETALLIC THIOLATE CLUSTER [J].
BLOCK, E ;
GERNON, M ;
KANG, H ;
LIU, SC ;
ZUBIETA, J .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) :1031-1033
[6]   THE TRANSITION FROM MOLECULES TO SOLIDS - MOLECULAR SYNTHESES OF NI9TE6(PET3)8, NI20TE18(PET3)12, AND NITE [J].
BRENNAN, JG ;
SIEGRIST, T ;
STUCZYNSKI, SM ;
STEIGERWALD, ML .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (26) :9240-9241
[7]   SYNTHESIS AND STRUCTURE OF THE [NI38PT6(CO)48H6-N]N- (N=5, 4) IONS - NI-PT CLUSTERS AS MODELS FOR CHERRY CRYSTALLITES [J].
CERIOTTI, A ;
DEMARTIN, F ;
LONGONI, G ;
MANASSERO, M ;
MARCHIONNA, M ;
PIVA, G ;
SANSONI, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1985, 24 (08) :697-698
[8]   METAL-MERCAPTIDE CHEMISTRY - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE [CU(SC6H5)3]2- ANION - A RATIONAL SYNTHESIS AND THE STRUCTURE OF THE [CU4(SC6H5)6]2- CLUSTER [J].
COUCOUVANIS, D ;
MURPHY, CN ;
KANODIA, SK .
INORGANIC CHEMISTRY, 1980, 19 (10) :2993-2998
[9]   CRYSTAL AND MOLECULAR-STRUCTURE OF HEXA-(MU2-BENZENETHIOLATO)TETRACUPRATE(I) DIANION [J].
DANCE, IG ;
CALABRESE, JC .
INORGANICA CHIMICA ACTA, 1976, 19 (02) :L41-L42
[10]  
FACKLER JP, 1989, J AM CHEM SOC, V111, P6343
1234