SYNTHESIS OF FUNCTIONALLY SUBSTITUTED POLYSILANES USING TRIFLUOROMETHANESULFONIC ACID

被引：42
作者：
UHLIG, W [1 ]
机构：
[1] MAX PLANCK INST COAL RES,W-4330 MULHEIM,GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 03期
关键词：
D O I：
10.1016/0022-328X(91)86257-Q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cleavage of silicon phenyl bonds in phenylmethylpolysilane by CF3SO3H leads to triflate derivatives of polysilanes. The polymers react with lithium derivatives or acidic element hydrogen compounds under formation of numerous substituted polysilanes.
引用
收藏
页码：C45 / C49
页数：5
相关论文
共 11 条
  • [1] THE SYNTHESIS OF FUNCTIONALIZED SILYLTRIFLATES
    BASSINDALE, AR
    STOUT, T
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 271 (1-3) : C1 - C3
  • [2] POLYDIMETHYLSILANES
    BURKHARD, CA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (03) : 963 - 964
  • [3] EMDE H, 1982, SYNTHESIS-STUTTGART, P1
  • [4] SYNTHESIS OF POLYSILANES
    HEINICKE, J
    UHLIG, W
    TZSCHACH, A
    REINHOLD, G
    [J]. ACTA POLYMERICA, 1990, 41 (10) : 538 - 543
  • [5] Organic derivatives of silicon Part XXX Complex silicohydrocarbons [SiPh2]n
    Kipping, FS
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1924, 125 : 2291 - 2297
  • [6] MATUJASZEWSKI K, 1987, POLYM PREPR, V28, P222
  • [7] POLYSILANE HIGH POLYMERS
    MILLER, RD
    MICHL, J
    [J]. CHEMICAL REVIEWS, 1989, 89 (06) : 1359 - 1410
  • [8] A NEW AND CONVENIENT SYNTHESIS OF ORGANOSILYLPHOSPHINES
    UHLIG, W
    TZSCHACH, A
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 576 (09): : 281 - 283
  • [9] SI-29 NUCLEAR MAGNETIC-RESONANCE OF DIMETHYL AND PHENYLMETHYL CONTAINING POLYSILANES
    WOLFF, AR
    NOZUE, I
    MAXKA, J
    WEST, R
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1988, 26 (03) : 701 - 712
  • [10] Zeigler J. M., 1987, POLYM PREPR AM CHEM, V28, P424
12