HYDROBORATION .62. MONOISOPINOCAMPHEYLBORANE, AN EXCELLENT CHIRAL HYDROBORATING AGENT FOR TRANS-DISUBSTITUTED AND TRISUBSTITUTED ALKENES - EVIDENCE FOR A STRONG STERIC DEPENDENCE IN SUCH ASYMMETRIC HYDROBORATIONS

被引：109
作者：
BROWN, HC
JADHAV, PK
MANDAL, AK
机构：
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1982年 / 47卷 / 26期
关键词：
D O I：
10.1021/jo00147a006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
引用
收藏
页码：5074 / 5083
页数：10
相关论文
共 18 条
[1]  
Brown, 1972, BORANES ORGANIC CHEM
[2]  
BROWN HC, 1977, ISRAEL J CHEM, V15, P12
[3]   ASYMMETRIC SYNTHESES VIA CHIRAL ORGANOBORANE REAGENTS [J].
BROWN, HC ;
JADHAV, PK ;
MANDAL, AK .
TETRAHEDRON, 1981, 37 (21) :3547-3587
[4]   HYDROBORATION .19. REACTION OF DIISOPINOCAMPHEYLBORANE WITH REPRESENTATIVE TRANS + HINDERED OLEFINS ( TRIISOPINOCAMPHEYLDIBORANE AS REAGENT FOR CONFIGURATIONAL ASSIGNMENT OF ALCOHOLS + OLEFINS VIA HYDROBORATION [J].
BROWN, HC ;
AYYANGAR, NR ;
ZWEIFEL, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (06) :1071-&
[5]   MONOISOPINOCAMPHEYLBORANE - NEW CHIRAL HYDROBORATING AGENT FOR RELATIVELY HINDERED (TRISUBSTITUTED) OLEFINS [J].
BROWN, HC ;
YOON, NM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (16) :5514-5516
[6]   ORGANOBORANES .27. EXPLORATION OF SYNTHETIC PROCEDURES FOR THE PREPARATION OF MONOISOPINOCAMPHEYLBORANE [J].
BROWN, HC ;
MANDAL, AK ;
YOON, NM ;
SINGARAM, B ;
SCHWIER, JR ;
JADHAV, PK .
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (26) :5069-5074
[7]   HYDROBORATION .18. REACTION OF DIISOPINOCAMPHEYLBORANE WITH REPRESENTATIVE CIS-ACYCLIC CYCLIC + BICYCLIC OLEFINS . CONVENIENT SYNTHESIS OF OPTICALLY ACTIVE ALCOHOLS + OLEFINS OF HIGH OPTICAL PURITY + ESTABLISHED CONFIGURATION [J].
BROWN, HC ;
AYYANGAR, NR ;
ZWEIFEL, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (03) :397-&
[8]  
BROWN HC, 1961, J AM CHEM SOC, V83, P486, DOI 10.1021/ja01463a055
[9]   SIMPLE SYNTHESIS OF MONOISOPINOCAMPHEYLBORANE OF HIGH OPTICAL PURITY [J].
BROWN, HC ;
SCHWIER, JR ;
SINGARAM, B .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (22) :4395-4397
[10]   HYDROBORATION .37. STRUCTURAL STUDY OF HYDROBORATION OF OLEFINS WITH THEXYLBORANE IN MOLAR RATIO OF 1=1 - CONVENIENT SYNTHESIS OF THEXYLMONOALKYLBORANES AND THEIR READY CONVERSION TO MONOALKYLBORANES [J].
BROWN, HC ;
NEGISHI, EI ;
KATZ, JJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (10) :2791-2798
12