METAL-COMPLEXES OF DYES .4. TRANSITION-METAL COMPOUNDS OF THE DIANIONS OF EPINDOLIDIONE AND 2,8-DIMETHYLEPINDOLIDIONE AS BIS(CHELATE) LIGANDS

被引：0

作者：

SCHMIDT, C ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 02期

关键词：

EPINDOLIDIONE; DIBENZO[B,G][1,5]NAPHTHYRIDIN-6,12(5,11H)-DIONE; METAL COMPLEXES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dianions of epindolidione and dimethylepindolidione act as bis(chelate) ligands (L) and form deep red polymeric complexes [L'ML]n (M = Ni(II), Co(II); L' = DMF, PEt3). They react with chloro bridged complexes [(R3P)MCl2]2 (M = Pd, Pt) and [(eta5-C5Me5)MCl2]2 (M = Rh, Ir) to give red bis-N,O-chelate complexes (R3P)(Cl)M-mu-L-M(Cl)(PR3) and (eta5-C5H5)(Cl)M-mu-L-M(Cl)(eta5-C5H5).

引用

页码：189 / 194

页数：6

共 17 条

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