FAST LITHIUM CONDUCTING GLASS-CERAMICS IN THE LI2O-CAO-TIO2-AL2O3-P2O5 SYSTEM

被引：34
作者：
HOSONO, H
ABE, Y
机构：
[1] Department of Materials Science and Engineering, Nagoya Institute of Technology, Showa-ku, Nagoya, 466, Gokiso-cho
来源：
SOLID STATE IONICS | 1991年 / 44卷 / 3-4期
关键词：
D O I：
10.1016/0167-2738(91)90021-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electrical conductivity was measured for the glasses and glass-ceramics with the composition (1+x)Li2O.6.6CaO.(4-2x)TiO2.xAl2O3.5.2P2O5 (mol ratio). High Li+-conducting glass-ceramics were obtained at around x = 0.4. The glass-ceramics are composed of LiTi2(PO4)3: Al, which is a fast Li+-conductor, and beta-Ca3(PO4)2 phases. The activation energy for the conduction was 29 kJ/mol, which is comparable to that in Li3N or LISICON. The conductivity at 300 K and 600 K is 5 x 10(-5) S/cm and 2 x 10(-2) S/cm, respectively, i.e. 5 to 7 orders of magnitude higher than those observed in the corresponding glasses.
引用
收藏
页码：293 / 297
页数：5
相关论文
共 13 条
  • [1] ABE Y, 1989, INORGANIC PHOSPHATE, pCH10
  • [2] IONIC-CONDUCTIVITY IN LI3N SINGLE-CRYSTALS
    ALPEN, UV
    RABENAU, A
    TALAT, GH
    [J]. APPLIED PHYSICS LETTERS, 1977, 30 (12) : 621 - 623
  • [3] IONIC-CONDUCTIVITY OF THE LITHIUM TITANIUM PHOSPHATE (LI1+XALXTI2-X(PO4)3), (LI1+XSCXTI2-X(PO4)3), (LI1+XYXTI2-X(PO4)3), (LI1+XLAXTI2-X(PO4)3 SYSTEMS
    AONO, H
    SUGIMOTO, E
    SADAOKA, Y
    IMANAKA, N
    ADACHI, GY
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (02) : 590 - 591
  • [4] BEALL GH, 1983, GLASS SCI TECHNOLOGY, V1, pCH7
  • [5] THE NASICON-TYPE TITANIUM PHOSPHATES LITI2(PO4)3, NATI2(PO4)3 AS ELECTRODE MATERIALS
    DELMAS, C
    NADIRI, A
    SOUBEYROUX, JL
    [J]. SOLID STATE IONICS, 1988, 28 : 419 - 423
  • [6] CRYSTAL STRUCTURE OF NAME2 4(PO4)3 - ME4 =GE TI ZR
    HAGMAN, LO
    KIERKEGA.P
    [J]. ACTA CHEMICA SCANDINAVICA, 1968, 22 (06): : 1822 - &
  • [7] POROUS NATI2(PO4)3 GLASS-CERAMICS
    HOSONO, H
    ABE, Y
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (10) : 3149 - 3151
  • [8] POROUS GLASS-CERAMIC IN THE CAO-TIO2-P2O5 SYSTEM
    HOSONO, H
    ZHANG, ZB
    ABE, Y
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1989, 72 (09) : 1587 - 1590
  • [9] IONIC-CONDUCTIVITY OF LITHIUM PHOSPHATE DOPED LITHIUM ORTHOSILICATE
    HU, YW
    RAISTRICK, ID
    HUGGINS, RA
    [J]. MATERIALS RESEARCH BULLETIN, 1976, 11 (10) : 1227 - 1230
  • [10] KISHIOKA A, 1974, B CHEM SOC JPN, V47, P2493, DOI 10.1246/bcsj.47.2493
12