S-TRANS-1,3-DIENES AS LIGANDS FOR CATIONIC GROUP-8 METAL CENTERS

被引：41

作者：

BENYUNES, SA ^{[1
]}

DAY, JP ^{[1
]}

GREEN, M ^{[1
]}

ALSAADOON, AW ^{[1
]}

WARING, TL ^{[1
]}

机构：

[1] UNIV LONDON KINGS COLL,DEPT CHEM,LONDON WC2R 2LS,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Dienes very frequently assume an s-cis-conformation upon coordination to metal centers. The Ru-complex 1 is the first cationic s-trans-diene complex which is stable in solution at room temperature. Such complexes are conceivable as reactive intermediates in the catalytic reaction of conjugated dienes.

引用

页码：1416 / 1417

页数：2

共 11 条

[1]

Principles and Applications of Organotransition Metal Chemistry, (1987)

[2]

Erker G., Wicher J., Engel J., Rosenfeldt F., Dietrich W., Kruger C., J. Am. Chem. Soc., 102, pp. 6344-6346, (1980)

[3]

Nakamura A., Yasuda H., Angew. Chem., 99, pp. 745-764, (1987)

[4]

Angew. Chem. Inl. Ed. Engl., 26, (1987)

[5]

Erker G., Kruger C., Muller G., Adv. Organomet. Chem., 24, (1985)

[6]

Okamoto T., Yasuda H., Nakamura Y., Kai Y., Kanehisa N., Kasai N., J. Am. Chem. Soc., 110, (1988)

[7]

Christensen N.J., Hunter A.D., Legzdins P., (1989)

[8]

Benyunes S.A., Green M., Grimshire M.J., Organometallics, 8, pp. 2268-2270, (1989)

[9]

Crocker M., Green M., Morton C.E., Nagle K.R., Orpen A.G., J. Chem. Soc., Dalton Trans., 1985, pp. 2145-2153

[10]

Waring T.L.

← 1 2 →