DEPENDENCE OF POLY(3-ALKYLTHIOPHENE) FILM PROPERTIES ON ELECTROCHEMICAL POLYMERIZATION CONDITIONS AND ALKYL CHAIN-LENGTH

被引：13
|
作者：
WANG, SL [1 ]
TAKAHASHI, H [1 ]
YOSHINO, K [1 ]
TANAKA, K [1 ]
YAMABE, T [1 ]
机构：
[1] KYOTO UNIV,GRAD SCH ENGN,DIV MOLEC ENGN,KYOTO 606,JAPAN
来源：
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1990年 / 29卷 / 04期
关键词：
Conducting polymers; Conductivity; Cyclic voltammetry; Electrochemical polymerization; Electron spin resonance; Poly(3-alkylthiophene); Xray diffraction;
D O I：
10.1143/JJAP.29.772
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Conductivity of the poly(3-alkylthiophene) (PAT) films is strongly affected by the conditions of electrochemical polymerization. The oxidation potential is higher and the conductivities lower in the PAT films of longer alkyl chain length. On the other hand, ΔHpp is narrower and the spin concentration higher in the PAT films of shorter alkyl chain length. © 1990 The Japan Society of Applied Physics.
引用
收藏
页码：772 / 775
页数：4
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