CROSS-METATHESIS OF SOME FUNCTIONALIZED OLEFINS WITH CYCLOOLEFINS AND BICYCLOOLEFINS CATALYZED BY WCL6-SILICON-CONTAINING COCATALYST SYSTEMS

被引：15

作者：

BESPALOVA, NB

BOVINA, MA

SERGEEVA, MB

OPPENGEIM, VD

ZAIKIN, VG

机构：

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 90卷 / 1-2期

关键词：

HOMOGENEOUS CATALYSTS; METATHESIS; OLEFINS; SILICON-CONTAINING CATALYSTS; TUNGSTEN;

D O I：

10.1016/0304-5102(93)E0299-V

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Homogeneous catalysts WCl6-1,1,3,3-tetramethyl-1,3-disilacyclobutane and WCl6-dihydrodiphenylsilane allow cross-metathesis of cycloolefins (cyclopentene, cyclooctene) and norbornene with ethyl-4-pentenoate, allyl cyanide, allyltrimethylsilane. Self-metathesis of functionalized olefins with two unconjugated carbon-carbon bonds takes place with high yields and selectivity.

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页码：21 / 27

页数：7

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