LIQUID-PHASE CATALYTIC-HYDROGENATION USING PALLADIUM ALLOY MEMBRANES

被引:21
作者
FARRIS, TS [1 ]
ARMOR, JN [1 ]
机构
[1] AIR PROD & CHEM INC,7201 HAMILTON BLVD,ALLENTOWN,PA 18195
关键词
ALKENES; CYLCOHEXENE; HYDROGENATION; MEMBRANES; PALLADIUM ALLOYS;
D O I
10.1016/0926-860X(93)80004-A
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The hydrogenation of several liquid alkenes was studied over Pd/Ru alloy membranes in either metal or glass membrane reactors. For cyclohexene, cyclo-octadiene, and octadecene as liquids, conversions of ca. 2-5% were common in contrast to the facile conversion of acetylenic alcohols.
引用
收藏
页码:25 / 32
页数:8
相关论文
共 17 条
[1]  
ANDERSON MA, 1991, Patent No. 5006248
[2]   CATALYSIS WITH PERMSELECTIVE INORGANIC MEMBRANES [J].
ARMOR, JN .
APPLIED CATALYSIS, 1989, 49 (01) :1-25
[3]  
ARMOR JN, 1992, CHEMTECH, P557
[4]  
Bhave R. R, 1991, INORGANIC MEMBRANES, P64
[5]  
EGAN BZ, 1989, ORNL DE90004386 ORD
[6]  
FARRIS TS, 1992, 10TH P INT C CAT BUD
[7]  
GOTO R, 1970, CHEM ENG, V34, P35
[8]  
GRYAZNOV VM, 1986, PLATIN MET REV, V30, P68
[9]  
GRYAZNOV VM, 1981, DISCUSS FARADAY SOC, V72, P73
[10]  
GRYAZNOV VM, 1983, Patent No. 4388479