METAL ALKOXIDES - MODELS FOR METAL-OXIDES .7. TRINUCLEAR AND TETRANUCLEAR ALKYLIDYNE CLUSTERS OF TUNGSTEN SUPPORTED BY ALKOXIDE LIGANDS

被引：54

作者：

CHISHOLM, MH ^{[1
]}

FOLTING, K ^{[1
]}

HEPPERT, JA ^{[1
]}

HOFFMAN, DM ^{[1
]}

HUFFMAN, JC ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1985年 / 107卷 / 05期

关键词：

D O I：

10.1021/ja00291a024

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1234 / 1241

页数：8

共 21 条

[1] TUNGSTEN-TUNGSTEN TRIPLE BOND .8. DINUCLEAR ALKOXIDES OF TUNGSTEN(III) AND STRUCTURAL CHARACTERIZATION OF HEXAISOPROPOXYBIS(PYRIDINE)DITUNGSTEN, THE 1ST COMPOUND WITH 4-COORDINATED TUNGSTEN ATOMS UNITED BY A TRIPLE BOND [J].

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[2] THE TETRADECAISOPROPOXYDIHYDRIDOTETRATUNGSTEN STORY [J].

AKIYAMA, M ;

CHISHOLM, MH ;

COTTON, FA ;

EXTINE, MW ;

HAITKO, DA ;

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LITTLE, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) :779-784

[3] A NEW TYPE OF TRINUCLEAR CLUSTER COMPOUND - THE INCOMPLETE BICAPPED (OR HEMICAPPED) STRUCTURE IN [W3O(O2CCH3)6(H2O)3]ZNBR4.8H2O [J].

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[4] A NEW AQUEOUS CHEMISTRY OF ORGANOMETALLIC, TRINUCLEAR CLUSTER COMPOUNDS OF MOLYBDENUM [J].

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COTTON, FA ;

DORI, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :243-244

[5] TRINUCLEAR MO-MO-BONDED CLUSTER CATION WITH ONE OXYGEN ATOM CAP AND ONE ETHYLIDYNE CAP [J].

BINO, A ;

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (19) :5779-5784

[6]

Chisholm M.F., UNPUB

[7] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES - W2(MU-C2H2)REVERSIBLE2W=CH [J].

CHISHOLM, MH ;

FOLTING, K ;

HOFFMAN, DM ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) :6794-6805

[8] METAL METAL BONDS AND METAL-CARBON BONDS IN THE CHEMISTRY OF MOLYBDENUM AND TUNGSTEN ALKOXIDES [J].

CHISHOLM, MH .

POLYHEDRON, 1983, 2 (08) :681-722

[9] METAL ALKOXIDES-MODELS FOR METAL-OXIDES .1. PREPARATIONS AND STRUCTURES OF HEXADECAALKOXYTETRATUNGSTEN COMPOUNDS, W4(OR)16, WHERE R = ME AND ET, AND OCTAOXOTETRAISOPROPOXYTETRAPYRIDINOTETRAMOLYBDENUM, MO4(O)4(MU-O)2(MU-3-O)2(O-IOTA-PR)2(MU-O-IOTA-PR)2(PY)4 [J].

CHISHOLM, MH ;

HUFFMAN, JC ;

KIRKPATRICK, CC ;

LEONELLI, J ;

FOLTING, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (20) :6093-6099

[10] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .5. COUPLING OF ALKYNE LIGANDS IN REACTIONS INVOLVING DITUNGSTEN HEXAALKOXIDES - AN ALTERNATIVE TO THE METATHESIS REACTION M=M+-C=C--]2M=C [J].

CHISHOLM, MH ;

HOFFMAN, DM ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) :6806-6815

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