CALORIMETRIC STUDIES OF THE NEUTRALIZATION OF POLYGALACTURONIC ACID

被引：1
|
作者：
RUDANTASIC, D
KLOFUTAR, C
机构：
[1] Department of Food Science and Technology, Biotechnical Faculty, University of Ljubljana
来源：
THERMOCHIMICA ACTA | 1994年 / 246卷 / 01期
关键词：
CALORIMETRY; COUNTERION; NEUTRALIZATION; PGA; POLYGALACTURONIC ACID; SUBUNIT;
D O I：
10.1016/0040-6031(94)85087-9
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Calorimetric data are reported on the enthalpy of neutralization of polygalacturonic acid obtained during its neutralization by either tetraalkylammonium or alkaline hydroxide solution. Thermometric curves are evaluated and discussed in terms of six equivalent equations, and the successive enthalpies of neutralization of previously chosen oligomeric subunits of polygalacturonic acid are determined. Together with the potentiometric data, this information provides a complete thermodynamic picture of the effect of the size of the alkyl group and the nature of the counterion on the dissociation behaviour of the polyacid in dilute aqueous solutions.
引用
收藏
页码：25 / 32
页数：8
相关论文
共 50 条
  • [21] CALORIMETRIC STUDIES OF SPECIAL CEMENTS
    KURDOWSKI, F
    NOCUNWCZELIK, W
    JOURNAL OF THERMAL ANALYSIS, 1995, 45 (05): : 923 - 930
  • [22] The potential physiological implications of polygalacturonic acid-mediated production of superoxide
    Spasojevic, Ivan
    Pristov, Jelena Bogdanovic
    PLANT SIGNALING & BEHAVIOR, 2010, 5 (12) : 1525 - 1529
  • [23] In situ forming hydrogel composed of hyaluronate and polygalacturonic acid for prevention of peridural fibrosis
    Cheng-Yi Lin
    Hsiu-Hui Peng
    Mei-Hsiu Chen
    Jui-Sheng Sun
    Tse-Ying Liu
    Ming-Hong Chen
    Journal of Materials Science: Materials in Medicine, 2015, 26
  • [24] Enantioselective Separation of Basic Drugs by CE with Polygalacturonic Acid as a Novel Chiral Selector
    Fenxia Zhu
    Yingxiang Du
    Jiaquan Chen
    Bin Chen
    Yanqian Zhu
    Xiang Zhai
    Shu Xu
    Wenhui Zhou
    Chromatographia, 2009, 69 : 1315 - 1320
  • [25] Production of narrow-range size-classes of polygalacturonic acid oligomers
    Cameron, Randall G.
    Luzio, Gary
    Baldwin, Elizabeth
    Narciso, Jan
    Plotto, Anne
    PROCEEDINGS OF THE 118TH ANNUAL MEETING OF THE FLORIDA STATE HORTICULTURAL SOCIETY, 2005, 118 : 406 - 409
  • [26] Synthesis of a disulfide cross-linked polygalacturonic acid hydrogel for biomedical applications
    Hsiu-Hui Peng
    Yi-Min Chen
    Chen-I Lee
    Ming-Wei Lee
    Journal of Materials Science: Materials in Medicine, 2013, 24 : 1375 - 1382
  • [27] Enzymatic production of pectic oligosaccharides from polygalacturonic acid with commercial pectinase preparations
    Combo, Agnan Marie Michel
    Aguedo, Mario
    Goffin, Dorothee
    Wathelet, Bernard
    Paquot, Michel
    FOOD AND BIOPRODUCTS PROCESSING, 2012, 90 (C3) : 588 - 596
  • [28] Enantioselective Separation of Basic Drugs by CE with Polygalacturonic Acid as a Novel Chiral Selector
    Zhu, Fenxia
    Du, Yingxiang
    Chen, Jiaquan
    Chen, Bin
    Zhu, Yanqian
    Zhai, Xiang
    Xu, Shu
    Zhou, Wenhui
    CHROMATOGRAPHIA, 2009, 69 (11-12) : 1315 - 1320
  • [29] Ibuprofen-conjugated hyaluronate/polygalacturonic acid hydrogel for the prevention of epidural fibrosis
    Lin, Cheng-Yi
    Peng, Hsiu-Hui
    Chen, Mei-Hsiu
    Sun, Jui-Sheng
    Chang, Chih-Ju
    Liu, Tse-Ying
    Chen, Ming-Hong
    JOURNAL OF BIOMATERIALS APPLICATIONS, 2016, 30 (10) : 1589 - 1600
  • [30] Eradication of Candida auris biofilm in vitro by a polygalacturonic and caprylic acid wound ointment
    Truong, Y. -Lan
    Rosenblatt, Joel
    Gerges, Bahgat
    Jiang, Ying
    Raad, Issam
    JOURNAL DE MYCOLOGIE MEDICALE, 2024, 34 (04):
12345