PORPHYRIN SPONGES - CONSERVATION OF HOST STRUCTURE IN OVER 200 PORPHYRIN-BASED LATTICE CLATHRATES

被引：406

作者：

BYRN, MP

CURTIS, CJ

HSIOU, Y

KHAN, SI

SAWIN, PA

TENDICK, SK

TERZIS, A

STROUSE, CE

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

[2] DEMOCRITOS NUCL RES CTR,INST MAT SCI,GR-15310 ATHENS,GREECE

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 21期

关键词：

D O I：

10.1021/ja00074a013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of the molecular packing in over 200 tetraarylporphyrin-based lattice clathrates reveals a strong conservation of host structure. In most cases, formation of porphyrin-based clathrates can be viewed as arising from intercalation of guest molecules into pure host materials. Several modes of intercalation are detected, and characteristic of intercalate structures, staging is observed. Intercalate formation accounts for the relative insensitivity of the host structure to the nature and size of the guest species. The structural conservation observed in this large class of materials facilitates rational modification of the host lattice. Crystallographic data are provided for 75 new porphyrin-based clathrates.

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页码：9480 / 9497

页数：18

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