NICKEL-CATALYZED SUBSTITUTION-REACTIONS OF ALLYLIC COMPOUNDS WITH SOFT NUCLEOPHILES - AN EFFICIENT ALTERNATIVE TO PALLADIUM CATALYSIS

被引：49

作者：

BRICOUT, H ^{[1
]}

CARPENTIER, JF ^{[1
]}

MORTREUX, A ^{[1
]}

机构：

[1] ENSCL,CHIM ORGAN APPL GRP,CATALYSE HETEROGENE & HOMOGENE LAB,CNRS,URA 402,F-59652 VILLENEUVE DASCQ,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 18期

关键词：

D O I：

10.1039/c39950001863

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substitution reactions of allyl alcohol derivatives la-e with diethylamine, phenol and dimethyl malonate are efficiently carried out in the presence of Ni(dppb)(2) (dppb = 1,2-diphenylphosphinobutane) as catalyst and ammonium salts or bases as-promoters or co-reagents.

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页码：1863 / 1864

页数：2

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