ELECTRONIC DECAY PROCESSES FOLLOWING THE RESONANCE EXCITATION OF THE B-1S-CORE ELECTRON IN BF3

被引：22

作者：

UEDA, K

CHIBA, H

SATO, Y

HAYAISHI, T

SHIGEMASA, E

YAGISHITA, A

机构：

[1] UNIV TSUKUBA,INST APPL PHYS,TSUKUBA,IBARAKI 305,JAPAN

[2] NATL LAB HIGH ENERGY PHYS,PHOTON FACTORY,TSUKUBA,IBARAKI 305,JAPAN

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 05期

关键词：

D O I：

10.1063/1.467537

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron spectroscopy has been carried out to investigate spectator and participant resonance Auger decay processes following the B 1-->2a(2)('') excitation in gaseous BF3 molecules using monochromatized synchrotron radiation. The resonance-enhanced satellite bands corresponding to the spectator Auger electron emission form six broad peaks showing good correspondence with the normal Auger bands. Resonance enhancement of the photolines corresponding to the participant Auger electron emission occurs only for the bonding orbitals having B character.

引用

页码：3520 / 3523

页数：4

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