ELECTRONIC DECAY PROCESSES FOLLOWING THE RESONANCE EXCITATION OF THE B-1S-CORE ELECTRON IN BF3

被引：22
|
作者：
UEDA, K
CHIBA, H
SATO, Y
HAYAISHI, T
SHIGEMASA, E
YAGISHITA, A
机构：
[1] UNIV TSUKUBA,INST APPL PHYS,TSUKUBA,IBARAKI 305,JAPAN
[2] NATL LAB HIGH ENERGY PHYS,PHOTON FACTORY,TSUKUBA,IBARAKI 305,JAPAN
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 05期
关键词：
D O I：
10.1063/1.467537
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Electron spectroscopy has been carried out to investigate spectator and participant resonance Auger decay processes following the B 1-->2a(2)('') excitation in gaseous BF3 molecules using monochromatized synchrotron radiation. The resonance-enhanced satellite bands corresponding to the spectator Auger electron emission form six broad peaks showing good correspondence with the normal Auger bands. Resonance enhancement of the photolines corresponding to the participant Auger electron emission occurs only for the bonding orbitals having B character.
引用
收藏
页码：3520 / 3523
页数：4
相关论文
共 50 条
  • [1] Mapping potential energy surfaces by core electron excitation:: the resonant Auger decay spectrum of BF3
    Miron, C
    Feifel, R
    Björneholm, O
    Svensson, S
    de Brito, AN
    Sorensen, SL
    Piancastelli, MN
    Simon, M
    Morin, P
    CHEMICAL PHYSICS LETTERS, 2002, 359 (1-2) : 48 - 54
  • [2] DIRECT OBSERVATION OF CORRELATION BETWEEN ELECTRON-EMISSION AND FRAGMENTATION INTO IONS FOLLOWING B-1S EXCITATION OF THE BF3 MOLECULE
    UEDA, K
    OHMORI, K
    OKUNISHI, M
    CHIBA, H
    SHIMIZU, Y
    SATO, Y
    HAYAISHI, T
    SHIGEMASA, E
    YAGISHITA, A
    PHYSICAL REVIEW A, 1995, 52 (03): : R1815 - R1818
  • [3] SHAPE-RESONANCE-ENHANCED VIBRATIONAL-EXCITATION OF BF3 BY ELECTRON-IMPACT
    TRONC, M
    MALEGAT, L
    AZRIA, R
    LECOAT, Y
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1982, 15 (07) : L253 - L257
  • [4] Symmetries and dissociation dynamics of F 1s core excited states of BF3
    Shimizu, Y
    Ueda, K
    Chiba, H
    Okunishi, M
    Ohmori, K
    West, JB
    Sato, Y
    Hayaishi, T
    JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (07): : 2419 - 2423
  • [5] Vibrationally Resolved B 1s Photoionization Cross Section of BF3
    Ayuso, D.
    Kimura, M.
    Kooser, K.
    Patanen, M.
    Plesiat, E.
    Argenti, L.
    Mondal, S.
    Travnikova, O.
    Sakai, K.
    Palacios, A.
    Kukk, E.
    Decleva, P.
    Ueda, K.
    Martin, F.
    Miron, C.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (23): : 5971 - 5978
  • [6] Vibrationally resolved B 1s photoionization cross section of BF3
    Ayuso, D.
    Kimura, M.
    Kooser, K.
    Patanen, M.
    Plesiat, E.
    Argenti, L.
    Mondal, S.
    Travni-kova, O.
    Sakai, K.
    Palacios, A.
    Kukk, E.
    Decleva, P.
    Ueda, K.
    Martin, F.
    Miron, C.
    XXIX INTERNATIONAL CONFERENCE ON PHOTONIC, ELECTRONIC, AND ATOMIC COLLISIONS (ICPEAC2015), PTS 1-12, 2015, 635
  • [7] Angle-resolved photoelectron and photoion study on the shape resonance in the B 1s ionization region of BF3
    Shimizu, Y
    Ueda, K
    Chiba, H
    Ohmori, K
    Okunishi, M
    Sato, Y
    Hayaishi, T
    JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (07): : 2415 - 2418
  • [8] Electronic structure, electronic decay, and desorption processes of molecular solid SiCl4 following core-level excitation
    Chen, JM
    Klauser, R
    Yang, SC
    Hsu, YJ
    Cheng, SI
    Wen, CR
    PHYSICAL REVIEW B, 1996, 54 (03): : 1455 - 1458
  • [9] Electronic structure, electronic decay, and desorption processes of molecular solid SiCl4 following core-level excitation
    Phys Rev B, 3 (1455):
  • [10] Nuclear motion and symmetry breaking of the B 1s-excited BF3 molecule
    Ueda, K
    De Fanis, A
    Saito, N
    Machida, M
    Kubozuka, K
    Chiba, H
    Muramatu, Y
    Sato, Y
    Czasch, A
    Jaguzki, O
    Dörner, R
    Cassimi, A
    Kitajima, M
    Furuta, T
    Tanaka, H
    Sorensen, SL
    Okada, K
    Tanimoto, S
    Ikejiri, K
    Tamenori, Y
    Ohashi, H
    Koyano, I
    CHEMICAL PHYSICS, 2003, 289 (01) : 135 - 147
12345