SILVER-SELECTIVE MEMBRANE ELECTRODES USING ACYCLIC DITHIA BENZENE DERIVATIVE NEUTRAL CARRIERS - COMPARISON WITH RELATED MACROCYCLIC-COMPOUNDS

被引：47
作者：
CASABO, J [1 ]
FLOR, T [1 ]
ROMERO, MI [1 ]
TEIXIDOR, F [1 ]
PEREZJIMENEZ, C [1 ]
机构：
[1] CSIC,INST CIENCIA MAT BARCELONA,E-08193 BARCELONA,SPAIN
来源：
ANALYTICA CHIMICA ACTA | 1994年 / 294卷 / 02期
关键词：
SENSORS; ACYCLIC DITHIA BENZENE DERIVATIVES; SILVER-SELECTIVE MEMBRANE ELECTRODES; MACROCYCLIC COMPOUNDS;
D O I：
10.1016/0003-2670(94)80196-7
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Four new acyclic dithia benzene derivatives have been synthesized: 1,3-bis[(ethylthio)methyl]benzene; 1,3-bis[(pentylthio)methyl]benzene; 1,3-bis[(octylthio)methyl]benzene, and 1,3-bis[(dodecylthio)methyl]benzene. All compounds have been tested as silver(I) ion sensors in membrane-based ion-selective electrodes, exhibiting good sensitivity, detection limits, reproducibility and selectivity. The chemical recognition of silver(I) by these receptors is compared to the behaviour presented by closely related macrocyclic and acyclic polythia compounds.
引用
收藏
页码：207 / 213
页数：7
相关论文
共 24 条
  • [1] FLOW-THROUGH TUBULAR PVC MATRIX MEMBRANE-ELECTRODE WITHOUT INNER REFERENCE SOLUTION FOR FLOW-INJECTION ANALYSIS
    ALEGRET, S
    ALONSO, J
    BARTROLI, J
    PAULIS, JM
    LIMA, JLFC
    MACHADO, AASC
    [J]. ANALYTICA CHIMICA ACTA, 1984, 164 (OCT) : 147 - 152
  • [2] BIOSENSORS BASED ON CONDUCTING FILLED POLYMER ALL-SOLID-STATE PVC MATRIX MEMBRANE ELECTRODES
    ALEGRET, S
    MARTINEZFABREGAS, E
    [J]. BIOSENSORS, 1989, 4 (05) : 287 - 297
  • [3] ALEGRET S, 1986, 2ND P INT M CHEM SEN, P751
  • [4] Anon, 1978, COMPENDIUM ANAL NOME, P168
  • [5] Baes C.F., 1976, HYDROLYSIS CATIONS
  • [6] SILVER(I) ION-SELECTIVE ELECTRODE BASED ON DITHIAMACROCYCLES
    CASABO, J
    PEREZJIMENEZ, C
    ESCRICHE, L
    ALEGRET, S
    MARTINEZFABREGAS, E
    TEIXIDOR, F
    [J]. CHEMISTRY LETTERS, 1990, (07) : 1107 - 1108
  • [7] SILVER(I) ION-SELECTIVE ELECTRODES BASED ON POLYTHIA-MACROCYCLES
    CASABO, J
    MESTRES, L
    ESCRICHE, L
    TEIXIDOR, F
    PEREZJIMENEZ, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08): : 1969 - 1971
  • [8] PYRIDINE-BASED MACROCYCLES CONTAINING N, O, AND S AND THEIR USE AS ION-SELECTIVE ELECTRODES - CRYSTAL-STRUCTURES OF 15-AZA-6-OXA-3,9-DITHIABICYCLO[9.3.1]PENTADECA-1(15),11,13-TRIENE AND (15-AZA-6-OXA-3,9-DITHIABICYCLO[9.3.1]PENTADECA-1(15),11,13-TRIENE)DICHLOROCOPPER(II)
    CASABO, J
    ESCRICHE, L
    ALEGRET, S
    JAIME, C
    PEREZJIMENEZ, C
    MESTRES, L
    RIUS, J
    MOLINS, E
    MIRAVITLLES, C
    TEIXIDOR, F
    [J]. INORGANIC CHEMISTRY, 1991, 30 (08) : 1893 - 1898
  • [9] CASABO J, UNPUB
  • [10] CLOSELY RELATED MACROCYCLIC AND ACYCLIC TRIDENTATE, PYRIDINE-DERIVATIVES, CONTAINING SULFUR, AND THEIR COMPLEXES - CRYSTAL-STRUCTURES OF (DICHLORO-3,10-DITHIA-16-AZABICYCLO[10.3.1]HEXADECA-1(16),12,14-TRIENE)COPPER(II) AND [2,6-BIS(ETHYLTHIOMETHYL)PYRIDINE]DICHLOROCOPPER(II)
    ESCRICHE, L
    SANZ, M
    CASABO, J
    TEIXIDOR, F
    MOLINS, E
    MIRAVITLLES, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (09): : 1739 - 1743
123