PHOTOCHEMICAL-REACTIONS OF [CIS-FE(H)(2)(ME(2)PCH(2)CH2(P)ME(2))(2)] WITH THIOPHENES - INSERTION INTO C-H AND C-S BONDS

被引：57

作者：

BUYS, IE ^{[1
]}

FIELD, LD ^{[1
]}

HAMBLEY, TW ^{[1
]}

MCQUEEN, AED ^{[1
]}

机构：

[1] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000557

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of [cis-Fe(H)(2)(dmpe)(2)] [dmpe = 1,2-bis(dimethylphosphino)ethane] in the presence of simple thiophenes gives products formed by insertion of the iron centre into both C-H and C-S bonds; the crystal structure of [Fe(SCMeCHCHCH)(dmpe)(2)] is a planar 'ferrathiacycle' but bond lengths and H-1 NMR spectroscopy indicate that this ring is best described as a localised diene structure rather than a 'ferrathiabenzene' with delocalised pi-system.

引用

页码：557 / 558

页数：2

共 17 条

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