COMPOUNDS WITH BRIDGEHEAD NITROGEN .71. STEREOCHEMISTRY OF PROTONATED PERHYDROPYRIDO[1,2-C][1,3]BENZOXAZEPINES

被引：1

作者：

CRABB, TA

FALLAH, A

机构：

[1] Department of Chemistry, Portsmouth Polytechnic, Portsmouth, Hampshire

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1993年 / 01期

关键词：

D O I：

10.1039/p29930000083

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Protonation of syn-perhydropyrido[1,2-c][1,3]benzoxazepines in CDCl3 solution by hydrogen chloride gas gives predominantly the trans-A/B ring fused hydrochloride salts. The corresponding anti-compounds give mixtures of hydrochlorides containing substantial amounts of the cis-salt. This latter compound prefers the O-outside cis-fused conformation.

引用

页码：83 / 86

页数：4

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