STATIC AND DYNAMIC STRUCTURES OF PENTACARBONYL-CHROMIUM(0) AND PENTACARBONYL-TUNGSTEN(0) COMPLEXES OF DITHIOETHER LIGANDS .1. SYMMETRICAL DITHIOETHER COMPLEXES AND X-RAY CRYSTAL-STRUCTURE OF [W(CO)5(TBUSCH2STBU)]

被引：10

作者：

ABEL, EW

ORRELL, KG

RAHOO, H

SIK, V

MAZID, MA

HURSTHOUSE, MB

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4RJ,DEVON,ENGLAND

[2] UNIV WALES COLL CARDIFF,COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 437卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)83443-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [M(CO)5(RSCH2SR)] (M = Cr, R = Et, (i)Pr,(t)Bu; M = W, R = Me, Et,(i)Pr,(t)Bu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. AG double dagger (298.15 K) values were in the range 34-42 kJ mol-1. An X-ray structure of [W(CO)5((t)BuSCH2StBu)] was obtained.

引用

页码：191 / 199

页数：9

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