EFFECTS OF THERMOPLASTIC ADDITIVES ON THE CURE OF UNSATURATED POLYESTER RESINS

被引：74
作者：
HSU, CP [1 ]
KINKELAAR, M [1 ]
HU, P [1 ]
LEE, LJ [1 ]
机构：
[1] OHIO STATE UNIV,DEPT CHEM ENGN,COLUMBUS,OH 43210
来源：
POLYMER ENGINEERING AND SCIENCE | 1991年 / 31卷 / 20期
关键词：
D O I：
10.1002/pen.760312003
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Thermoplastic additives tend to promote the phase separation during the reaction of unsaturated polyester resins. Consequently, they reduce the amount of shrinkage during curing. Several thermoplastic additives which resulted in significant different microstructure of cured resins were investigated. The effects of microstructure formation on the sol-gel transition, reaction kinetics, and gelation time were studied. The mechanism of microstructure formation and causes of macro-gelation were explained by the influence of thermoplastic additives on the particle formation rate and inter-particle reaction rate during curing.
引用
收藏
页码：1450 / 1460
页数：11
相关论文
共 23 条
  • [1] [Anonymous], 1975, POLYM HDB
  • [2] ATKINS KE, 1978, POLYM BLENDS, V2, pCH23
  • [3] Bartkus EJ, 1970, APPL POLYM SYMP, V15, P113
  • [4] Bidstrup S., 1986, THESIS U MINNESOTA
  • [5] BOBALEK EG, 1964, J APPL POLYM SCI, V8, P625
  • [6] PHASE-SEPARATION IN STYRENATED POLYESTER RESIN CONTAINING A POLYVINYL ACETATE) LOW-PROFILE ADDITIVE
    BUCKNALL, CB
    DAVIES, P
    PARTRIDGE, IK
    [J]. POLYMER, 1985, 26 (01) : 109 - 112
  • [7] HSU CP, IN PRESS POLYMER
  • [8] KIAEE L, 1988, AICHE S SER, V84, P52
  • [9] KROEKEL CH, 1968, JAN SAE AUT ENG C
  • [10] THE EFFECT OF PRESSURE ON THE CURING BEHAVIOR OF UNSATURATED POLYESTER RESINS
    LEE, DS
    HAN, CD
    [J]. POLYMER COMPOSITES, 1987, 8 (03) : 133 - 140
123