AN EXAMINATION OF THE INTERACTION OF SILANES CONTAINING CARBON CARBON DOUBLE-BONDS WITH ALUMINUM-OXIDE BY INELASTIC ELECTRON-TUNNELING SPECTROSCOPY

被引：5
|
作者：
COMYN, J
OXLEY, DP
PRITCHARD, RG
WERRETT, CR
KINLOCH, AJ
机构：
[1] Drs D.P. Oxley and R.G. Pritchard are with the School of Applied Physical Sciences, Leicester Polytechnic, Leicester, LE1 9BH
[2] Dr C.R. Werrett is now with ICI Chemicals and Polymers Limited, Billingham
[3] Dr A.J. Kinloch is with the Department of Mechanical Engineering, Imperial College, London
来源：
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES | 1990年 / 10卷 / 01期
关键词：
aluminium oxide; inelastic tunnelling spectroscopy; silanes; solution doping;
D O I：
10.1016/0143-7496(90)90022-P
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Inelastic electron tunnelling spectra were obtained for some silanes with CC bonds doped from solution in acidic aqueous alcohol and from their vapours. Spectra show a high level of hydrolysis of the silanes doped from solution, but only partial hydrolysis from vapour doping. Vinyltrichlorosilane is fully hydrolysed with both methods of doping. A silane containing a methacrylate group is partially saponified. © 1990.
引用
收藏
页码：13 / 18
页数：6
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