SYNTHESIS AND CHARACTERIZATION OF PORPHYRAZINOCTAMINE DERIVATIVES - X-RAY CRYSTALLOGRAPHIC STUDIES OF [2,3,7,8,12,13,17,18-OCTAKIS(DIBENZYLAMINO)-PORPHYRAZINATO]MAGNESIUM(II) AND (2,3,7,8,12,13,17,18-OCTAKIS[ALLYL(BENZYL)AMINO]-PORPHYRAZINATO)NICKEL(II)

被引：41

作者：

MANI, NS

BEALL, LS

MILLER, T

ANDERSON, OP

HOPE, H

PARKIN, SR

WILLIAMS, DJ

BARRETT, AGM

HOFFMAN, BM

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

[2] COLORADO STATE UNIV,DEPT CHEM,FT COLLINS,CO 80523

[3] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[4] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 18期

关键词：

D O I：

10.1039/c39940002095

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)ami no]-2Z-butene-1,4-dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(ll) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.

引用

页码：2095 / 2096

页数：2

共 10 条

[1] HYDROGEN-CYANIDE CHEMISTRY .8. NEW CHEMISTRY OF DIAMINOMALEONITRILE - HETEROCYCLIC SYNTHESIS [J].