REDUCTIVE DEOXYGENATION USING HYDRIDOZIRCONIUM ENOLATES - A NEW SYNTHESIS OF ALPHA,BETA-UNSATURATED ESTERS

被引：21

作者：

GODFREY, AG ^{[1
]}

GANEM, B ^{[1
]}

机构：

[1] CORNELL UNIV,BAKER LAB,DEPT CHEM,ITHACA,NY 14853

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 49期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)60795-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unusual new reaction of Cp2ZrHCl transforms beta-ketoesters into alpha,beta-unsaturated esters in one step and provides a useful alternative to the traditional, three-step process of reduction, mesylation/tosylation, and elimination.

引用

页码：7461 / 7464

页数：4

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