REDUCTIVE DEOXYGENATION USING HYDRIDOZIRCONIUM ENOLATES - A NEW SYNTHESIS OF ALPHA,BETA-UNSATURATED ESTERS

被引：21
|
作者：
GODFREY, AG [1 ]
GANEM, B [1 ]
机构：
[1] CORNELL UNIV,BAKER LAB,DEPT CHEM,ITHACA,NY 14853
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 49期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(00)60795-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unusual new reaction of Cp2ZrHCl transforms beta-ketoesters into alpha,beta-unsaturated esters in one step and provides a useful alternative to the traditional, three-step process of reduction, mesylation/tosylation, and elimination.
引用
收藏
页码：7461 / 7464
页数：4
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