A MANGANESE TRIS QUINONE OXIMATO PAIR REVEALING NEW STRUCTURES AND MAGNETIC-PROPERTIES IN MNIII,II CHEMISTRY

被引：28

作者：

BASU, P ^{[1
]}

CHAKRAVORTY, A ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and isomerism of the first tris-chelated low-spin Mn(III) (1a) and Mn(II) (1b) pair of complexes [MnL3]0,-, of the 4-chloro-o-benzoquinone oxime ligand HL is described; MnL3 has strong preference for mer-geometry but mer- and fac-isomers coexist in solution as well as in the crystal lattice of the [Et4N]+ salt of [MnL3]-.

引用

页码：809 / 810

页数：2

共 23 条

[1]

BALAUCH D, 1988, J CHEM SOC CHEM COMM, P1178

[2] REDOX IN A FERROVERDIN ANALOG - RECOGNITION OF ISOMERIC COORDINATION SPHERES BY FEII AND FEIII [J].

BASU, P ;

PAL, S ;

CHAKRAVORTY, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (15) :977-978

[3] 1ST EXAMPLE OF A MIXED-SPIN TRINUCLEAR MANGANESE(II) COMPLEX - [MNN6(S=1/2)][MNO6(S=5/2)][MNN6(S=1/2)] [J].

BASU, P ;

PAL, S ;

CHAKRAVORTY, A .

INORGANIC CHEMISTRY, 1988, 27 (11) :1848-1850

[4] CHEMISTRY OF FERROVERDINS AND FERRIVERDINS - IRON REDOX AND GEOMETRICAL STEREODYNAMISM [J].

BASU, P ;

CHOUDHURY, SB ;

PAL, S ;

CHAKRAVORTY, A .

INORGANIC CHEMISTRY, 1989, 28 (13) :2680-2686

[5]

Basu P., UNPUB

[6] STUDIES ON METAL-COMPLEXES OF ORTHO-QUINONE MONOOXIMES .9. ANALYSIS OF THE CHARGE-DISTRIBUTION WITHIN THE ORTHO-QUINONE MONOOXIME LIGANDS THROUGH CRYSTALLOGRAPHIC DATA [J].

CARUGO, O ;

DJINOVIC, K ;

RIZZI, M ;

CASTELLANI, CB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (05) :1255-1258

[7] SYNTHESIS AND STRUCTURE OF A TRINUCLEAR MANGANESE(II) COMPLEX CONTAINING LOW-SPIN METAL [J].

CHATTOPADHYAY, S ;

BASU, P ;

PAL, S ;

CHAKRAVORTY, A .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (12) :3829-3833

[8] THE OXIDATIVE ISOMERIZATION OF CIS,CIS-DICARBONYLMANGANESE(I) DERIVATIVES - ISOLATION OF THE RESULTING TRANS-DICARBONYLMANGANESE(II) COMPLEXES AND THE X-RAY STRUCTURE OF CIS,CIS-[MNBR(CO)2(P(OPH)3)(PH2PCH2PPH2)] [J].

CONNELLY, NG ;

HASSARD, KA ;

DUNNE, BJ ;

ORPEN, AG ;

RAVEN, SJ ;

CARRIEDO, GA ;

RIERA, V .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (06) :1623-1629

[9]

COOKE AM, 1955, J P PHYS SOC A, V68, P32

[10]

COTTON FA, 1909, J INORG NUCL CHEM, V10, P28

← 1 2 3 →