POTENTIAL FUNCTION OF INTERNAL-ROTATION OF (CH3)2CCLNO, CH3CCL2NO, AND THEIR DEUTERIUM ANALOGS

被引：0

作者：

TREPALIN, SV

YARKOV, AV

SOKOLOV, VB

IVANOV, AN

机构：

[1] Institute of Physiologically Active Substances, Academy of Sciences of the USSR, Chernogolovka

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 03期

关键词：

D O I：

10.1007/BF00959564

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potential function has been constructed for internal rotation of the NO-group in (CH3)2CClNO, CH3CCl2NO, and their deuterium analogs. It has been established that the N=O bond in the cisCl conformer of CH3CCl2NO does not eclipse the C-Cl bond, rather forming an angle of approximately 30‡. It has been shown that a change in substitutent on the α-carbon atom may produce a substantial change in the form of the potential function of internal rotation (PFIR) of the NO group. © 1990 Plenum Publishing Corporation.

引用

页码：476 / 480

页数：5

共 10 条

[1]

ABRAMENKOV AV, 1981, ZH STRUKT KHIM, V22, P42

[2]

CRADOCK S, 1986, J MOL STRUCT, V40, P199

[3] MICROWAVE, INFRARED, AND RAMAN-SPECTRA, CONFORMATIONAL STABILITY, STRUCTURE, DIPOLE-MOMENT, AND VIBRATIONAL ASSIGNMENT FOR CYCLOPROPYL ISOCYANATE [J].