SHAPE EFFECTS IN 2-DIMENSIONAL HARD MOLECULE FLUIDS

被引：12

作者：

GOULDING, CW

RIGBY, M

机构：

[1] Department of Chemistry, King’s College, Strand, London

来源：

MOLECULAR PHYSICS | 1992年 / 75卷 / 03期

关键词：

D O I：

10.1080/00268979200100451

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Two-dimensional hard molecule fluids, comprising diatomic and triatomic fused hard discs, have been studied by Monte Carlo simulation, and the effects of changes in molecular shape on the equation of state investigated. The virial coefficients, B2-B5, have also been calculated for all the molecules. Various approaches to the equations of state for these systems have been considered. A modified form of scaled particle theory appears to be the most generally successful.

引用

页码：623 / 631

页数：9

共 12 条

[1]

ALLEN MP, 1987, COMPUTER SIMULATION, pCH4

[2] SERIES REPRESENTATION OF THE EQUATION OF STATE FOR HARD PARTICLE FLUIDS [J].