FLAVIN-MEDIATED PHOTOLYSIS OF MYCOSPORINES

被引:18
作者
BERNILLON, J [1 ]
PARUSSINI, E [1 ]
LETOUBLON, R [1 ]
FAVREBONVIN, J [1 ]
ARPIN, N [1 ]
机构
[1] UNIV LYON 1,BIOL & TECHNOL MEMBRANES LAB,CNRS,UMR 9,F-69622 VILLEURBANNE,FRANCE
关键词
2-hydroxy glutaric acid; aminocyclohexenone; mycosporine glutamine; Mycosporines; photolysis mediated by flavins; photoproduts;
D O I
10.1016/0031-9422(90)89015-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Under aerobic conditions and in the presence of flavins, light causes the photolysis of mycosporine glutamine into aminocyclohexenone and 2-hydroxy glutaric acid. This photolysis, which is temperature dependent, is also observed when other photosensitizers which are carriers of singlet oxygen replace flavins. This photodestruction also occurs with mycosporine amino alcohols but at reduced rate and probably by another mechanism. © 1990.
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页码:81 / 84
页数:4
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