SODIUM TETRAPHENYLBORATE AS A PHENYLATING REAGENT IN THE PALLADIUM-CATALYZED PHENYLATION OF ALKENES AND ACID-CHLORIDES

被引：0

作者：

CHO, CS ^{[1
]}

ITOTANI, K ^{[1
]}

UEMURA, S ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT HYDROCARBON CHEM,KYOTO 60601,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 443卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sodium tetraphenylborate (NaBPh4) reacts with terminal alkenes in acetic acid at 25-degrees-C in the presence of a catalytic amount of palladium(II) acetate together with silver acetate as a re-oxidant to give the corresponding phenylated alkenes in 22-87% yield. It also reacts with acid chlorides in tetrahydrofuran (THF) at 25-degrees-C in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) to give the corresponding phenyl ketones in 51-100% yield. Carbonylation of the borate with 1-30 atm carbon monoxide (CO) in methanol at 25-degrees-C in the presence of palladium(II) acetate or sodium chloropalladate (Na2PdCl4) affords a low yield (9-30%) of benzophenone and methyl benzoate, a higher pressure favoring the formation of the latter.

引用

页码：253 / 259

页数：7