trans-Bis(nitrato-kappa O)tetrakis(1-vinyl-1H-imidazole-kappa N-3)copper(II)

被引：5

作者：

Sen, Fatih ^{[1
]}

Sahin, Ramazan ^{[2
]}

Andac, Omer ^{[2
]}

Tas, Murat ^{[3
]}

机构：

[1] Kilis 7 Aralik Univ, Vocat High Sch Hlth Serv, Dept Opticianry, TR-79000 Kilis, Turkey

[2] Ondokuz Mayis Univ, Arts & Sci Fac, Dept Chem, TR-55139 Samsun, Turkey

[3] Giresun Univ, Arts & Sci Fac, Dept Chem, TR-28000 Giresun, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 19.3; disorder in main residue; mean σ(C-C) = 0.004 Å; R factor = 0.041; single-crystal X-ray study; T = 296 K; wR factor = 0.109;

D O I：

10.1107/S1600536812030607

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(NO3)(2)(C5H6N2)(4)], the Cu-II ion is located on an inversion centre. It features a Jahn-Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6): 0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions.

引用

页码：M1045 / +

页数：8

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