THE PREPARATION OF METALLA-SULFUR SELENIUM COMPLEXES FROM REACTIONS IN LIQUID-AMMONIA

被引：0
|
作者：
WOOLLINS, JD
机构：
来源：
JOURNAL DE PHYSIQUE IV | 1991年 / 1卷 / C5期
关键词：
D O I：
10.1051/jp4:1991525
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The preparation of metalla-sulphur-nitrogen and metalla-selenium-nitrogen complexes from reactions in liquid ammonia is described. For example, reaction of PtCl2(PR3)2 with [S4N3]Cl in liquid ammonia yields Pt(S2N2)(PR3)2. Similar reactions with SOCl2, SO2Cl2 and SeCl4 give complexes containing NSO-, [SO2(NH)2]2- and Se2N2(2-) ligands respectively.
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页码：217 / 222
页数：6
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