DIFFUSION AND SOLUBILITY OF HCL IN ICE - PRELIMINARY-RESULTS

被引:37
作者
DOMINE, F
THIBERT, E
VANLANDEGHEM, F
SILVENTE, E
WAGNON, P
机构
[1] Cnrs, Laboratoire de Glaciologie Et Géophysique de L'environnement, St Martin D'hères
关键词
D O I
10.1029/94GL00512
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
The diffusion and solubility of HCl in ice have been measured between -5 and -15-degrees-C by exposing large single crystals of ice to low vapor pressures of HCl for several days. The solubility is found to be (1.0+/-0.15) x 10(-4) mol/l at -15-degrees-C under a 5.6x10(4) Pa HCl partial pressure. The diffusion coefficient is of the order of 10(-12) cm2s-1 at -8-degrees-C, but the determination of the value is affected by small angle boundaries, where HCl motion is much faster. Extrapolation of these results suggests that HCl is not incorporated into stratospheric ice crystals.
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收藏
页码:601 / 604
页数:4
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