FARNESYL DIPHOSPHATE SYNTHASE REACTIONS WITH DIMETHYLALLYL DIPHOSPHATE ANALOGS HAVING OXYGEN-ATOMS IN THEIR CHAINS

被引:11
|
作者
MAKI, Y [1 ]
KURIHARA, M [1 ]
ENDO, T [1 ]
ABIKO, M [1 ]
SAITO, K [1 ]
WATANABE, G [1 ]
OGURA, K [1 ]
机构
[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN
关键词
D O I
10.1246/cl.1995.389
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Six dimethylallyl diphosphate analogues having oxygen atoms in their alkyl chains were found to act as substrate in the reaction catalyzed by pig liver farnesyl diphosphate synthase to give geranyl diphosphate analogues or farnesyl diphosphate analogues. The number of IPP incorporated into the product depended on not only the length of the chain but also its hydrophobicity.
引用
收藏
页码:389 / 390
页数:2
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