ATTACK OF ISOCYANIDE AND CARBON-MONOXIDE ON A BRIDGING ALKYLIDYNE LIGAND AT A DITUNGSTEN CENTER - CLEAVAGE OF THE C-N AND C-O TRIPLE BONDS WITH RESPECTIVE FORMATION OF TUNGSTEN IMIDO AND TUNGSTEN-OXO GROUPS AND CONCOMITANT ADDITION OF THE CARBON-ATOM TO THE BRIDGING ALKYLIDYNE CARBON YIELDING A BRIDGING SIGMA-W1, ETA-2-W2 ALKYNYL LIGAND

被引：23

作者：

CHISHOLM, MH ^{[1
]}

HEPPERT, JA ^{[1
]}

HUFFMAN, JC ^{[1
]}

STREIB, WE ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1985年 / 24期

关键词：

D O I：

10.1039/c39850001771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1771 / 1773

页数：3

共 25 条

[1] STEREOCHEMICAL CONTROL OF ALKYNE OLIGOMERIZATION AT A DIRUTHENIUM CENTER - X-RAY STRUCTURES OF [RU2(CO)(MU-CO)(MU-C4H4CME2)(ETA-C5H5)2] AND [RU2(MU-CO)[MU-C4(CO2ME)4CH2](ETA-C5H5)2] [J].

ADAMS, PQ ;

DAVIES, DL ;

DYKE, AF ;

KNOX, SAR ;

MEAD, KA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (05) :222-224

[2] TETRAKIS(TRIMETHYLSILYLMETHYL)BIS(MU-TRIMETHYLSILYLMETHYLIDYNE)DITUNGSTEN [J].

ANDERSEN, RA ;

GALYER, AL ;

WILKINSON, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (10) :609-609

[3] SYNTHESIS, X-RAY CRYSTAL-STRUCTURE, AND NMR-STUDIES OF TRANS-BIS(DIMETHYLPHENYLPHOSPHINE)BIS[(DICARBIDO(4-)SIGMA-PT,SIGMA-W1,ETA-2-W2)-PENTAKIS(TERT-BUTOXY)DITUNGSTEN(M=M)]PLATINUM(II) [J].

BLAU, RJ ;

CHISHOLM, MH ;

FOLTING, K ;

WANG, RJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (22) :1582-1584

[4] PHOTOCHEMICAL-REACTION OF MU-ETHENYLIDENE COMPLEX [(C5H5)(CO)FE]2(MU-CO)(MU-C=CH2) WITH ACETYLENES [J].

CASEY, CP ;

MILES, WH ;

FAGAN, PJ ;

HALLER, KJ .

ORGANOMETALLICS, 1985, 4 (03) :559-563

[5]

Chisholm M.F., UNPUB

[6] MOLECULAR-STRUCTURE AND DYNAMIC SOLUTION BEHAVIOR OF THE BRIDGING 1,3-DIMETALLAALLYL LIGAND IN (ME3SICH2)4W2(MU-CSIME3)(MU-C3R2SIME3) COMPOUNDS (R=H,ME,PH) FORMED BY INSERTION OF ALKYNES INTO A BRIDGING ALKYLIDYNE LIGAND [J].

CHISHOLM, MH ;

HEPPERT, JA ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (04) :1151-1153

[7] DETAILED STRUCTURE OF BIS(MU-TRIMETHYLSILYLMETHYLIDYNE)-TETRAKIS(TRIMETHYLSILYLMETHYL)DITUNGSTEN(W-W) [J].

CHISHOLM, MH ;

COTTON, FA ;

EXTINE, MW ;

MURILLO, CA .

INORGANIC CHEMISTRY, 1978, 17 (03) :696-698

[8] 1,3-DITUNGSTACYCLOBUTADIENES .1. REACTIONS WITH ALKYNES - ALKYNE ADDUCTS AND 1,3-DIMETALLAALLYL DERIVATIVES [J].

CHISHOLM, MH ;

HUFFMAN, JC ;

HEPPERT, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (18) :5116-5136

[9]

CHISHOLM MH, UNPUB J CHEM SOC CHE

[10]

FAGAN PJ, 1982, J AM CHEM SOC, V104, P4950

← 1 2 3 →