SYNTHESIS OF ME2SI-ETA-5-C5H4(CO)FE(CO)2-FE(CO)-ETA-5-C5H4SIME2 AND A NOVEL REACTION BETWEEN ITS SI-SI AND FE-FE BONDS

被引：64

作者：

SUN, HL ^{[1
]}

XU, SS ^{[1
]}

ZHOU, XZ ^{[1
]}

WANG, HG ^{[1
]}

WANG, RJ ^{[1
]}

YAO, XK ^{[1
]}

机构：

[1] NANKAI UNIV,CTR ANAL & CALCULAT,TIANJIN 300071,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 444卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83094-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Me2Si-eta5-C5H4(CO)Fe(CO)2Fe(CO)-eta5-C5H4SiMe2 (1) was synthesized by reaction of 1,2-bis(cyclopentadienyl)tetramethyldisilane and pentacarbonyliron. An unexpected product, Me2Si-eta5-C5H4 Fe(CO)2SiMe2-eta5-C5H4Fe(CO)2 (2), was obtained from the reaction, which was evidently formed via a novel metathesis reaction between Si-Si and Fe-Fe bonds in 1. The molecular structures of 1 and 2 were determined by single-crystal X-ray diffraction studies.

引用

页码：C41 / C43

页数：3

共 10 条

[1] METAL-METAL BONDING IN CO-ORDINATION COMPLEXES .9. CRYSTAL STRUCTURE OF TRANS-DI-MU-CARBONYL-DICARBONYLDI-PI-CYCLOPENTADIENYLDI-IRON (FE-FE), A REDETERMINATION [J].

BRYAN, RF ;

GREENE, PT .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (18) :3064-&

[2] REACTIVITY PATTERNS OF METAL-CARBONYL ANIONS AND THEIR DERIVATIVES [J].

ELLIS, JE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 86 (01) :1-56

[3] PREPARATION AND REACTIVITY OF THE NEW CYCLOPENTADIENYL-BRIDGED COMPLEX (ME2SICH2CH2SIME2)(C5H4FE(CO)2)2 [J].

JANDA, KD ;

MCCONNELL, WW ;

NELSON, GO ;

WRIGHT, ME .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 259 (02) :139-143

[4] PREPARATION OF ORGANOSILYL-SUBSTITUTED AND ORGANOGERMYL-SUBSTITUTED FERROCENES [J].

KUMADA, M ;

MIMURA, K ;

KONDO, T ;

KONDO, M ;

YAMAMOTO, K ;

IKEDA, S ;

ISHIKAWA, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 43 (02) :293-&

[5] ORGANOMETALLOIDAL DERIVATIVES OF THE TRANSITION-METALS .9. SYNTHESIS AND THE CRYSTAL-STRUCTURE OF (ETA-5C5H5)FE(CO)2SIME2-SIPH3 [J].

PARKANYI, L ;

PANNELL, KH ;

HERNANDEZ, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 252 (02) :127-132

[6]

RAZUVAEV GA, 1986, RUSS CHEM REV, V55, P606

[7]

Sun H., UNPUB

[8] SYNTHESIS AND CRYSTAL-STRUCTURE OF A DINUCLEAR IRON TETRACARBONYL COMPLEX CONTAINING A LIGAND, ETA-5,ETA-5-C5ME4CH2CH2CH2C5ME4 [J].

TOBITA, H ;

HABAZAKI, H ;

SHIMOI, M ;

OGINO, H .

CHEMISTRY LETTERS, 1988, (06) :1041-1044

[9] CRYSTAL AND MOLECULAR-STRUCTURE OF DI-MU-CARBONYL-CIS-MU-(1-5-ETA-1'-5'-ETA-DICYCLOPENTADIENYLDIMETHYLSILANE)BIS(CARBONYLIRON)(FE-FE) [J].

WEAVER, J ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (14) :1439-1443

[10] TRANSITION-METAL COMPLEXES OF NOVEL RING-BRIDGED BIS(N5-CYCLOPENTADIENYL)LIGANDS - THEIR SYNTHESIS, CHEMISTRY, AND STRUCTURAL CHARACTERIZATION [J].

WEGNER, PA ;

USKI, VA ;

KIESTER, RP ;

DABESTANI, S ;

DAY, VW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (14) :4846-4848

← 1 →