Theoretical Study of the Transesterification of Triglycerides to Biodiesel Fuel under Various Conditions

被引：5

作者：

Asakuma, Y. ^{[1
]}

Kawanamil, O. ^{[1
]}

Maeda, K. ^{[1
]}

Kuramochi, H. ^{[2
]}

Fukuil, K. ^{[1
]}

机构：

[1] Univ Hyogo, Himeji, Hyogo, Japan

[2] Natl Inst Environm Study, Tsukuba, Ibaraki, Japan

来源：

INTERNATIONAL JOURNAL OF THERMODYNAMICS | 2011年 / 14卷 / 04期

关键词：

Biodiesel fuel; transesterification reaction; electrostatic potential;

D O I：

10.5541/ijot.301

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The transesterification of triglycerides under various conditions was considered in terms of the activation energy obtained from molecular orbital calculations. The transesterification reaction proceeds via a cyclic transition state, consisting of the carboxyl carbon and the alcohol. Moreover, the reaction pathway was shown by an activation energy analysis and an electrostatic potential distribution.

引用

收藏

页码：193 / 196

页数：4

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