IONIC-CONDUCTIVITY OF AND PHASE-TRANSITION IN LITHIUM THIOPHOSPHATE LI3PS4

被引：306
|
作者：
TACHEZ, M
MALUGANI, JP
MERCIER, R
ROBERT, G
机构：
[1] Univ de Franche-Comte, Lab, d'Electrochimie des Solides,, Besancon, Fr, Univ de Franche-Comte, Lab d'Electrochimie des Solides, Besancon, Fr
来源：
SOLID STATE IONICS | 1984年 / 14卷 / 03期
关键词：
DIFFERENTIAL THERMAL ANALYSIS - Applications - ELECTRIC MEASUREMENTS - Conductivity - ELECTROLYTES - Testing - LITHIUM COMPOUNDS - Electric Conductivity;
D O I：
10.1016/0167-2738(84)90097-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A phase transition of Li//3PS//4 has been revealed at 190 degree C both by DTA and by a discontinuity in the Arrhenius plots of conductivity. The conductivity is increased by a step of 0. 5, and the low and high temperature ranges are characterized by activation energies of respectively 0. 49 ( plus or minus 0. 01) ev and 0. 46 ( plus or minus 0. 01) ev. A small order-disorder of the Li** plus ion distribution might be the source of this phenomenon; Li//3PS//4 may be considered as a good lithium crystalline electrolyte.
引用
收藏
页码：181 / 185
页数：5
相关论文
共 50 条
  • [1] Crystal structure and phase transitions of the lithium ionic conductor Li3PS4
    Homma, Kenji
    Yonemura, Masao
    Kobayashi, Takeshi
    Nagao, Miki
    Hirayama, Masaaki
    Kanno, Ryoji
    SOLID STATE IONICS, 2011, 182 (01) : 53 - 58
  • [2] Copper Thiophosphate (Cu3PS4) as an Electrode Material for Lithium Solid-State Batteries with Lithium Thiophosphate (β-Li3PS4) Electrolyte
    Zhang, Zhenggang
    Mazzio, Katherine A.
    Riegger, Luise M.
    Brehm, Wolfgang
    Janek, Juergen
    Sann, Joachim
    Adelhelm, Philipp
    ENERGY TECHNOLOGY, 2023, 11 (10)
  • [3] Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4
    Liu, Zengcai
    Fu, Wujun
    Payzant, E. Andrew
    Yu, Xiang
    Wu, Zili
    Dudney, Nancy J.
    Kiggans, Jim
    Hong, Kunlun
    Rondinone, Adam J.
    Liang, Chengdu
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (03) : 975 - 978
  • [4] Copper Thiophosphate (Cu3PS4) as an Electrode Material for Lithium Solid-State Batteries with Lithium Thiophosphate ( β- Li3PS4) Electrolyte
    Zhang, Zhenggang
    Mazzio, Katherine A.
    Riegger, Luise M.
    Brehm, Wolfgang
    Janek, Juergen
    Sann, Joachim
    Adelhelm, Philipp
    ENERGY TECHNOLOGY, 2023,
  • [5] Crystal Structure of High-Temperature Phase of Lithium Ionic Conductor, Li3PS4
    Homma, Kenji
    Yonemura, Masao
    Nagao, Miki
    Hirayama, Masaaki
    Kanno, Ryoji
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2010, 79
  • [6] IONIC-CONDUCTIVITY AND PHASE-TRANSITION IN THIN SILVER TELLURIDE FILMS
    KRUPNIKOV, ES
    ALIEV, FY
    ABDULLAEV, AG
    FIZIKA TVERDOGO TELA, 1980, 22 (08): : 2468 - 2471
  • [7] IONIC-CONDUCTIVITY OF AGCRSE2 IN THE REGION OF PHASE-TRANSITION
    ANTROPOV, VM
    KONEV, VN
    PLESHCEV, VG
    ROGAL, NP
    FIZIKA TVERDOGO TELA, 1984, 26 (08): : 2545 - 2547
  • [8] Improvement of lithium ionic conductivity of Li3PS4 through suppression of crystallization using low-boiling-point solvent in liquid-phase synthesis
    Takahashi, Masakuni
    Yang, Seunghoon
    Yamamoto, Kentaro
    Ohara, Koji
    Phuc, Nguyen Huu Huy
    Watanabe, Toshiki
    Uchiyama, Tomoki
    Sakuda, Atsushi
    Hayashi, Akitoshi
    Tatsumisago, Masahiro
    Muto, Hiroyuki
    Matsuda, Atsunori
    Uchimoto, Yoshiharu
    SOLID STATE IONICS, 2021, 361
  • [9] Elucidating the Role of Microstructure in Thiophosphate Electrolytes - a Combined Experimental and Theoretical Study of β-Li3PS4
    Ates, Tugce
    Neumann, Anton
    Danner, Timo
    Latz, Arnulf
    Zarrabeitia, Maider
    Stepien, Dominik
    Varzi, Alberto
    Passerini, Stefano
    ADVANCED SCIENCE, 2022, 9 (18)
  • [10] Preparation of nanoporous β-Li3PS4 solid electrolyte with high ionic conductivity by wet chemical method
    Li Jiu-yong
    Liu Wei-ming
    Zhang Xiao-feng
    Ma Yi-bo
    Chen Mu
    Qiu Ran-feng
    Yan Yue
    CAILIAO GONGCHENG-JOURNAL OF MATERIALS ENGINEERING, 2019, 47 (09): : 101 - 107
12345