INCOHERENT NEUTRON-SCATTERING STUDY OF PROTONIC CONDUCTORS

被引：13
作者：
LASSEGUES, JC
CAVAGNAT, D
机构：
[1] Laboratoire de Spectroscopie Moléculaire et Cristalline, Université de Bordeaux I, 33405 Talence Cédex
来源：
PHYSICA B | 1992年 / 180卷
关键词：
D O I：
10.1016/0921-4526(92)90422-O
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Incoherent neutron scattering results are presented for two typical proton conducting systems: aqueous solutions of strong acids and fused phosphoric acid. The quasielastic profiles are analyzed in terms of mean proton translational and rotational diffusive motions. The presence and possible origin of an additional quasielastic component is then discussed in terms of proton exchange, damped oscillatory modes or collective excitations. More generally, the authors try to survey the advantages and limitations of the neutron scattering technique for a study of the proton conduction mechanism in liquids and solutions.
引用
收藏
页码：645 / 650
页数：6
相关论文
共 24 条
[1]  
BEE M, 1988, APPLICATION QUASIELA
[2]   INCOHERENT QUASIELASTIC NEUTRON-SCATTERING FROM H2O AND AQUEOUS ZNCL2 SOLUTIONS [J].
BELLISSENTFUNEL, MC ;
KAHN, R ;
DIANOUX, AJ ;
FONTANA, MP ;
MAISANO, G ;
MIGLIARDO, P ;
WANDERLINGH, F .
MOLECULAR PHYSICS, 1984, 52 (06) :1479-1486
[3]   ABSENCE OF FAST H(+)-ION MOTION IN AQUEOUS HCL - A NEUTRON-SCATTERING STUDY [J].
BERTAGNOLLI, H ;
CHIEUX, P ;
HERTZ, HG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 :687-695
[4]   NEW ANALYSIS OF THE NEUTRON-DIFFRACTION DATA FOR ANHYDROUS ORTHO-PHOSPHORIC ACID AND THE STRUCTURE OF H3PO4 MOLECULES IN CRYSTALS [J].
BLESSING, RH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1988, 44 :334-340
[5]  
Bockris JGM., 1970, MODERN ELECTROCHEMIS, DOI [10.1007/978-1-4615-8600-5, DOI 10.1007/978-1-4615-8600-5]
[6]   NEUTRON-SCATTERING STUDY OF THE PROTON DYNAMICS IN ACIDIC SOLUTIONS [J].
CAVAGNAT, D ;
LASSEGUES, JC .
SOLID STATE IONICS, 1991, 46 (1-2) :11-17
[7]  
CHEN SH, 1986, ADV CHEM PHYS, V4, P1
[8]   PROTON TRANSPORT MECHANISM IN CONCENTRATED AQUEOUS-SOLUTIONS AND SOLID HYDRATES OF ACIDS [J].
DIPPEL, T ;
KREUER, KD .
SOLID STATE IONICS, 1991, 46 (1-2) :3-9
[9]  
Egelstaff P. A., 1967, INTRO LIQUID STATE
[10]  
EIGEN M, 1964, PROG REACT KINET, V2, P287
123