SYNTHESIS AND CHARACTERIZATION OF MONO-ARIZIDINE AND BIS-AZIRIDINE BIS-DIMETHYLGLYOXIMATO COBALT(III) COMPLEXES

被引：4

作者：

WARE, DC ^{[1
]}

MACKIE, DS ^{[1
]}

BROTHERS, PJ ^{[1
]}

DENNY, WA ^{[1
]}

机构：

[1] UNIV AUCKLAND,SCH MED,CANC RES LAB,AUCKLAND,NEW ZEALAND

来源：

POLYHEDRON | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1016/S0277-5387(00)84328-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses of the neutral bis-dimethylglyoximato [(DH)2] dimethylsulphide (DMS) cobalt(III) complexes, [Co(DH)2(DMS)X] (X = Cl, Br, I, SeCN), are described. Substitution of the DMS ligand in these complexes by aziridine (Az) produces the neutral complexes [Co(DH)2(Az)X] (X = Cl, Br, I, SeCN), containing one aziridine ligand. The syntheses of the cationic bis-aziridine complex [Co(DH)2(AZ)2]Cl and its bis-diphenylglyoximato (DpgH) analogue [Co(DpgH)2(Az)2]Cl are also described.

引用

页码：1371 / 1376

页数：6

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