OXIDATION OF HALOGENATED PROPANES WITH METHYLOSINUS-TRICHOSPORIUM (OB3B)

被引：3

作者：

SHIMODA, M ^{[1
]}

SEKI, Y ^{[1
]}

OKURA, I ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT BIOENGN,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 83卷 / 1-2期

关键词：

ALCOHOL DEHYDROGENASE; BACTERIAL OXIDATION; HALOALKANE OXIDATION; METHANE MONOOXYGENASE; METHYLOSINUS-TRICHOSPORIUM;

D O I：

10.1016/0304-5102(93)87002-P

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Halogenated propanes (1-chloropropane, 1-bromopropane, 2-chloropropane, and 2-bromopropane) were oxidized with Methylosinus trichosporium (OB3b). 1-Propanol, 1-halogenated-2-propanol, and 1-halogenated-3-propanol were produced from 1-halogenated propane, and 2-halogenated-1-propanol and acetone were produced from 2-halogenated propane, showing that all the carbon atoms of the halogenated propanes were attacked by activated oxygen. The optical purity of halohydrin obtained from halogenated propane with M. trichosporium was independent of halogen type.

引用

页码：L5 / L10

页数：6

共 7 条

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SHIMODA, M
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