PT/SIO2 CATALYSTS - A COMPARISON OF THE IMPREGNATION AND THE SOL-GEL METHODS

被引:20
作者
BOSCH, P [1 ]
LOPEZ, T [1 ]
LARA, VH [1 ]
GOMEZ, R [1 ]
机构
[1] UNIV AUTONOMA METROPOLITANA IZTAPALAPA,DEPT CHEM,POB 55-534,MEXICO CITY 09340,DF,MEXICO
来源
JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 80卷 / 03期
关键词
HYDROGENATION; IMPREGNATION; PHENYLACETYLENE; PLATINUM; SILICA; SOL GEL PREPARATION;
D O I
10.1016/0304-5102(93)85004-D
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A comparative study of Pt/SiO2 catalysts prepared by impregnation or by the sol-gel method is reported. The catalysts were characterized by chemisorption, electron microscopy and X-ray diffraction studies. The results showed that metallic particles (35 angstrom) in sol-gel catalyst, are particles coming out from the support. These ''emerged particles'', in phenylacetylene hydrogenation, act like ultrahighly dispersed particles.
引用
收藏
页码:299 / 306
页数:8
相关论文
共 50 条
[31]   Methylcellulose/SiO2 hybrids: sol-gel preparation and characterization by XRD, FTIR and AFM [J].
Rangelova, Nadezhda ;
Radev, Lachezar ;
Nenkova, Sanchi ;
Miranda Salvado, Isabel M. ;
Vas Fernandes, Maria H. ;
Herzog, Michael .
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2011, 9 (01) :112-118
[32]   Nanostructured optical fibers in the SiO2/SnO2 system by the sol-gel method [J].
Granger, G. ;
Restoin, C. ;
Roy, P. ;
Jamier, R. ;
Rougier, S. ;
Lecomte, A. ;
Blondy, J. -M. .
MATERIALS LETTERS, 2014, 120 :292-294
[33]   Chemical resistance of SiO2 layers obtained by the sol-gel technique on a glass substrate [J].
Nocun, Marek ;
Sroda, Marcin ;
Ciecinska, Malgorzata .
OPTICA APPLICATA, 2015, 45 (01) :125-134
[34]   NEW APPROACH TO PREPARATION OF GELATINE/SiO2 HYBRID SYSTEMS BY THE SOL-GEL PROCESS [J].
Pietras, Przemyslaw ;
Przekop, Robert ;
Maciejewski, Hieronim .
CERAMICS-SILIKATY, 2013, 57 (01) :58-65
[35]   Fabrication of TiO2/SiO2 multilayer film structure by the sol-gel process with efficient thermal treatment methods [J].
Han, Koohee ;
Kim, Jung Hyeun .
APPLIED SURFACE SCIENCE, 2012, 263 :69-72
[36]   Effect of Sn Addition on n-Butane Dehydrogenation over Alumina-supported Pt Catalysts Prepared by Co-impregnation and Sol-gel Methods [J].
Kikuchi, Iori ;
Ohshima, Masa-aki ;
Kurokawa, Hideki ;
Miura, Hiroshi .
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2012, 55 (03) :206-213
[37]   Effects of catalyst on the transmittance and stability of SiO2 antireflective film prepared by sol-gel method [J].
Peng, Kun ;
Chen, E. ;
Zhou, Lingping ;
Zhu, Jiajun ;
Li, Deyi .
RESEARCH IN MATERIALS AND MANUFACTURING TECHNOLOGIES, PTS 1-3, 2014, 835-836 :462-465
[38]   Design and sol-gel preparation of SiO2/TiO2 and SiO2/SnO2/SiO2-SnO2 multilayer antireflective coatings [J].
Wang, Jindi ;
Ge, Juanjuan ;
Hou, Haigang ;
Wang, Mingsong ;
Liu, Guiwu ;
Qiao, Guanjun ;
Wang, Yongsheng .
APPLIED SURFACE SCIENCE, 2017, 422 :970-974
[39]   Effect of Concentration and Thermal Treatment on the Properties of Sol-Gel Derived CuO/SiO2 Nanostructure [J].
Tohidi, Sayed Hossein ;
Grigoryan, Garnik ;
Sarkeziyan, Verzhine ;
Ziaie, Farhood .
IRANIAN JOURNAL OF CHEMISTRY & CHEMICAL ENGINEERING-INTERNATIONAL ENGLISH EDITION, 2010, 29 (02) :27-35
[40]   Characterization of Grape Extract-Colored SiO2 Synthesized via the Sol-Gel Method [J].
Fiorentino, Marika ;
D'Angelo, Antonio ;
Vertuccio, Luigi ;
Khan, Humaira ;
Catauro, Michelina .
APPLIED SCIENCES-BASEL, 2024, 14 (24)