PT/SIO2 CATALYSTS - A COMPARISON OF THE IMPREGNATION AND THE SOL-GEL METHODS

被引:20
作者
BOSCH, P [1 ]
LOPEZ, T [1 ]
LARA, VH [1 ]
GOMEZ, R [1 ]
机构
[1] UNIV AUTONOMA METROPOLITANA IZTAPALAPA,DEPT CHEM,POB 55-534,MEXICO CITY 09340,DF,MEXICO
来源
JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 80卷 / 03期
关键词
HYDROGENATION; IMPREGNATION; PHENYLACETYLENE; PLATINUM; SILICA; SOL GEL PREPARATION;
D O I
10.1016/0304-5102(93)85004-D
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A comparative study of Pt/SiO2 catalysts prepared by impregnation or by the sol-gel method is reported. The catalysts were characterized by chemisorption, electron microscopy and X-ray diffraction studies. The results showed that metallic particles (35 angstrom) in sol-gel catalyst, are particles coming out from the support. These ''emerged particles'', in phenylacetylene hydrogenation, act like ultrahighly dispersed particles.
引用
收藏
页码:299 / 306
页数:8
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