ELECTROCHEMICAL ACETOXYLATION OF 2-METHYLNAPHTHALENE

被引：5
|
作者：
KOWALSKI, J
PLOSZYNSKA, J
机构：
[1] Department of General Chemistry, Faculty of Chemistry I, Łukasiewicz Technical University
来源：
ELECTROCHIMICA ACTA | 1990年 / 35卷 / 11-12期
关键词：
D O I：
10.1016/0013-4686(90)87073-B
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The oxidation of 2-methylnaphthalene in the solution of lithium acetate in glacial acetic acid has been investigated. It has been found that, within the range of potentials 1.10-1.25 V vs saturated mercury acetate electrode in glacial acetic acid, the oxidation process results in mono- and diacetates of 2-methylnaphthalene formation. The values of Eτ/4 for 2-methylnaphthalene, 1-acetate-2-methylnaphthyl and 1,4-diacetate-2-methylnaphthyl oxidation have been determined as 1.09, 1.05 and 1.13 V, respectively. The degree of 2-methylnaphthalene conversion to monoacetate reaches its maximum value at 1.25 V which is 32.8%. © 1990.
引用
收藏
页码：1739 / 1742
页数：4
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