CRYSTAL-STRUCTURES AND ELECTRICAL RESISTIVITIES OF 3-COMPONENT ORGANIC CONDUCTORS - (BEDT-TTF)(2)MM'(SCN)(4) [M=K, RB, CS M'=CO, ZN, CD]

被引：77
|
作者：
MORI, H
TANAKA, S
MORI, T
MARUYAMA, Y
机构：
[1] TOKYO INST TECHNOL, DEPT ORGAN & POLYMER MAT, TOKYO 152, JAPAN
[2] INST MOLEC SCI, OKAZAKI, AICHI 444, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 04期
关键词：
D O I：
10.1246/bcsj.68.1136
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New three-component organic conductors, (BEDT-TTF)(2)MM'(SCN)(4) [M=K, Rb, Ca; M'=Co, Zn, Cd], are prepared. The crystal structure analyses of alpha-ET(2)CsCo(SCN)(4), ETZn(SCN)(3), alpha-ET(2)RbZn(SCN)(4), alpha-ET(2)CsZn(SCN)(4), alpha-ETCd(0.66)(SCN)(2), and ET(2)CsCd(SCN)(4) are carried out. Most of salts have the a-type donor arrangement and the polymer sheet like [...M('2+)...(SCN)(-)...M(+)...] in a thick anion layer. Especially alpha-(BEDT-TTF)2 CsM'(SCN)(4) [M'=Co and Zn] are metallic down to 20 K.
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收藏
页码：1136 / 1144
页数：9
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