PALLADIUM CATALYZED CASCADE CYCLOADDITION REACTIONS - GENERAL CONCEPTS AND ILLUSTRATIVE EXAMPLES

被引:62
作者
GRIGG, R [1 ]
KENNEWELL, P [1 ]
TEASDALE, A [1 ]
SRIDHARAN, V [1 ]
机构
[1] ROUSSEL SCI INST,SWINDON SN3 5BZ,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)60081-3
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A general palladium catalysed cycloaddition strategy is proposed involving initial oxidative - addition of alkyl -, aryl - and vinyl - halides to Pd(0) followed intermolecular carbopalladation and subsequent intramolecular carbopalladation leading to ring formation. Examples of 5 - and 6 - ring formation are given.
引用
收藏
页码:153 / 156
页数:4
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