ASYMMETRICAL COMPLEXATION AND SIMULTANEOUS ELECTROCHEMICAL RECOGNITION OF 2 DIFFERENT GROUP 2 METAL-CATIONS BY A 1,1'-FERROCENE-BIS(METHYLENE AZA-18-CROWN-6) RECEPTOR

被引：14

作者：

CHEN, Z ^{[1
]}

PILGRIM, AJ ^{[1
]}

BEER, PD ^{[1
]}

机构：

[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 23期

关键词：

D O I：

10.1039/ft9959104331

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Voltammetric (CV, SWV) and fast atom bombardment mass spectrometric evidence demonstrates for the first time that a 1,1'-ferrocene-bis(methylene aza-18-crown-6) receptor (L) is capable of asymmetrically complexing and electrochemically recognising two different Group 2 metal cations (Ba2+, Mg2+) simultaneously in acetonitrile solution.

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页码：4331 / 4333

页数：3

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