GELATION - A REVIEW

被引:105
作者
DJABOUROV, M
机构
[1] Ecole de Physique et Chimie, Laboratoire de Physique Thermique, CNRS URA 857, Paris, 75231, 10, Rue Vauquelin
关键词
GELATION; PERCOLATION; RHEOLOGY; NETWORK STRUCTURE; POLYMERS; COLLOIDS;
D O I
10.1002/pi.4990250302
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper reviews the modern ideas on the process of gelation which have arisen from the analogy between gelation and percolation. The basic features which are common to all types of gels, colloidal or polymeric systems are first recalled; then after a simplified presentation of the percolation model, a few examples illustrating these concepts are chosen (for chemical gelation, a copolymerisation reaction and for physical gelation, the gelatin sol-gel transition). In conclusion, electron micrographs of gel networks (gelatin gel and an inorganic gel of thorium phosphate) are shown, which reveal the great diversity and complexity of the structures.
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页码:135 / 143
页数:9
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